BASF CORPORATION -- POAST HERBICIDE, 598135 -- 6840-00N003839
===================== Product Identification ===================== Product ID:POAST HERBICIDE, 598135 MSDS Date:10/10/1996 FSC:6840 NIIN:00N003839 Status Code:A === Responsible Party === Company Name:BASF CORPORATION Box:13528 City:RESEARCH TRIANGLE PARK State:NC ZIP:27709 Country:US Info Phone Num:919-547-2000 Emergency Phone Num:800-832-4357 Chemtrec Ind/Phone:(800)424-9300 CAGE:1T774 === Contractor Identification === Company Name:BASF CORPORATION Box:13528 City:RESEARCH TRIANGLE PARK State:NC ZIP:27709 Country:US Phone:919-547-2000 CAGE:1T774 ============= Composition/Information on Ingredients ============= Ingred Name:SETHOXYDIM; MOL. WGHT: 327.5. CHEMICAL NAME FOR SETHOXYDIM: 2-(1-(ETHOXYIMINO)BUTYL)-5-(2(ETHYLTHIO)PROPYL)-3-HYDROXY-2-CYCLOHE XEN-1-ONE CAS:74051-80-2 RTECS #:GW7191000 Code:F = Wt:18. Ingred Name:HEAVY AROMATIC SOLVENT NAPHTHA (PETROLEUM); (PETROLEUM SOLVENT) CAS:64742-94-5 RTECS #:WF3100000 = Wt:68. OSHA PEL:100 PPM ACGIH TLV:100 PPM Ingred Name:NAPHTHALENE CAS:91-20-3 RTECS #:OJ0525000 = Wt:7. OSHA PEL:50 MG/M3;10 PPM OSHA STEL:15 PPM ACGIH TLV:52 MG/M3;10 PPM ACGIH STEL:79 MG/M3;15 PPM EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:NON-IONIC EMULSIFIER CAS:9016-45-9 RTECS #:AX0247000 = Wt:7. ===================== Hazards Identification ===================== Effects of Overexposure:HLTH HAZ: EFFECTS, INCLUDING HEADACHE, DIZZINESS, DROWSINESS & CONFUSION. INGESTION CAUSES NAUSEA, VOMITING, BLURRED VISION & CNS DISORDERS. ASPIRATION OF LIQUID INTO LUNGS MAY RESULT IN CHEMICAL PNEU MONITIS, WHICH MAY BE FATAL. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DEFATTING & DERMATITIS. Medical Cond Aggravated by Exposure:THOSE WITH PRIOR BLOOD DISEASES MAY BE MORE SEVERELY AFFECTED. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY WASH WITH RUNNING WATER FOR AT LEAST 15 MINUTES. IF IRRITATION DEVELOPS, CONSULT MD. SKIN: WASH AFFECTED AREAS WITH PLENTY OF SOAP & WATER. IF IRRITATOIN DEVELOPS, CONSULT MD. INGEST ION: DO NOT INDUCE VOMITING. DILUTE WITH WATER & GET IMMEDIATE MEDICAL ATTENTION. NEVER GIVE FLUIDS OR INDUCE VOMITING IF VICTIM IS UNCONSCIOUS OR HAVING CONVULSIONS. INHALATION: MOVE TO FRESH AIR. AI D IN BREATHING, IF NECESSARY, & GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:=62.8C, 145.F AS SOLVENT Autoignition Temp:=443.C, 829.4F Autoignition Temp Text:APPROX Lower Limits:1.3% @ 20C Upper Limits:5.3% @ 103C Extinguishing Media:USE WATER FOG, FOAM OR DRY CHEMICAL EXTINGUISHING MEDIA. Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE. NFPA 704 HAZARD CODES: HEALTH - 2; FLAMMABLE - 2; REACTIVITY - 1. ================== Accidental Release Measures ================== Spill Release Procedures:ELIM ALL IGNIT SOURCES. WEAR RUBBER GLOVES, GOGGLES & BOOTS WHEN CLEANING UP LIQ SPILL. RECOVER & APPLY ACCORDING TO LBL WHENEVER POSS; OTHERWISE, COVER CONTAM AREA W/ABSORB MATL UNTIL DRY. SPILLS SHO ULD BE CONTAINED, SOLIDIFIED & PLACED IN SUITABLE CNTNRS FOR DISP IN LICENSED FACILITY. HAZARDOUS SUBSTANCE SUPERFUND: YES. (RQ AS PRODUCT 1430 LBS). RQ (LBS): 100 (NAPHTHALENE) ====================== Handling and Storage ====================== Handling and Storage Precautions:NFPA 30 STORAGE CLASSIFICATION: IIIA. DO NOT GET INTO EYES OR ON CLOTHING. KEEP OUT OF REACH OF CHILDREN. Other Precautions:(IF YOU DO NOT UNDERSTAND THE LABEL, FIND SOMEONE TO READ IT TO YOU IN DETAIL.) CONTROL MEASURES/PERSONAL PROTECTIVE EQUIPMENT PERTAINS TO RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING & PACK AGING WORKERS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPROVED SUPPLIED AIR RESPIRATORS SHOULD BE WORN IF LARGE QUANTITIES OF VAPORS ARE GENERATED OR PROLONGED EXPOSURE POSSIBLE. Ventilation:WHENEVER POSSIBLE, ENGINEERING CONTROLS SHOULD BE USED TO MINIMIZE THE NEED FOR PERSONAL PROTECTIVE EQUIPMENT. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . LONG SLEEVE SHIRT & SLACKS. Supplemental Safety and Health PHYSICAL DATA: BULK DENSITY: 7.80 LBS/GAL. REACTIVITY DATA: CORROSIVE TO METAL: NO. OXIDIZER: NO. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:NOT DETERMINED Vapor Pres:2 MM HG @ 20C Spec Gravity:0.935 G/ML pH:4.0-5.0 (AS IS) Solubility in Water:FORMS EMULSION Appearance and Odor:LIGHT AMBER LIQUID; AROMATIC ODOR. (INTENSITY: MODERATE). ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENT. Stability Condition to Avoid:HEAT, AIR, MOISTURE. Hazardous Decomposition Products:SO*2, NO*X DURING COMBUSTION. =================== Toxicological Information =================== Toxicological Information:FOR POAST HERBICIDE (FORMULATED PRODUCT): LD50:(DERMAL,RAT) >5 G/KG. LC50:(INHAL,RAT) >4.6 MG/L (4 HOURS). RABBIT, EYE & SKIN IRRITATION - MODERATELY IRRITATING. GUINEA PIG, DERMAL SENSITIZATION - NON -SENSITIZING. THE FOLLOWING SPECIAL STUDIES HAVE BEEN PERFORMED FOR THE ACTIVE INGREDIENT: SKIN SENSITIZATION (GUINEA PIG) - NEGATIVE. TERATOGENICITY (RAT & RABBIT) - NEGATIVE. REPRODUCTION STUDIES (2 GENERATIONS RAT) - NEGATIVE. ===================== Ecological Information ===================== Ecological:PESTICIDE APPLICATORS & WORKERS MUST REFER TO PRODUCT LABEL & DIRECTIONS FOR USE ATTACHED TO PRODUCT FOR AGRICULTURAL USE REQUIREMENTS I/A/W EPA WORKER PROTECTION STANDARD 40 CFR PART 170. EPA REG NO: 7969-58. ENVIRONMENTAL TOXICITY DATA: POAST HERBICIDE HAS LOW AVIAN TOXICITY & IS NOT TOXIC TO BEES. BLUEGILL SUNFISH 96 HR LC50 = 1.6 MG/L. RAINBOW TROUT 96 HR LC50 = 1.2 MG/L. DAPHNIA MAGNA 48 HR L C50 = 2.6 MG/L. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . APPLY ACCORDING TO LBL WHENEVER POSS. DO NOT DISCHARGE INTO WATERWAYS/SEWER SYSTEMS W/OUT PROPER AUTHORITY. HAZ WASTE 40 CFR 261: NO. CNTNR DISP:TRI RINSE CAN INTO SPRAYER. DISPOSE OF CNTNR IN INCINERATOR/LANDFILL EPA-APPRVD FOR PESTICIDE CNTNRS. C ONSULT W/DISP AUTHS FOR APPRVD ALTERNATIVE PROCS. =================== MSDS Transport Information =================== Transport Information:DOT PROPER SHIPPING NAME(49 CFR 172.101-102):BULK - COMBUST LIQ, NOS-. PKG - NONE. HAZ SUBSTANCE(PER PKG)(49 CFR CERCLA LIST)(0.2%):YES - NAPHTHALENE. RQ:100. DOT HAZ CLASSIFICATION(CFR 172.101-102) P RIMARY:BULK - COMBUST LIQ(120 GALS/MORE).PKG - NONE. SECONDARY:NONE. DOT LBLS REQD(49 CFR 172.101-102):NONE. DOT PLACARDS REQD(CFR 172.504): COMBUST "1993". POIS CONSTITUENT(49 CFR 172.203(K)):NONE. B ILL OF LADING DESCRIPTION:BULK - COMBUST LIQ, NOS- (CNTNS PETRO DISTILS), NA 1993, PG III, RQ(NAPHTHALENE), MARINE POLLUTANT, ERG 128. PKG - CMPDS, TREE/WEED KILLING, (HERBICIDES), NOIBN. CC NO:431 (N ON-BULK); D72 (BULK). UN/NA CODE:1993. ===================== Regulatory Information ===================== SARA Title III Information:SARA TITLE III SECTION 313: NAPHTHALENE LISTED. SARA 311/312 REPORTING: FIRE: YES. PRESSURE: NO. REACTIVITY: NO. ACUTE: YES. CHRONIC: YES. TPQ: 10,000 LBS. State Regulatory Information: Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.