DOW CHEMICAL U.S.A. -- DURSBAN (R) 6R INSECTICIDAL CONCENTRATE -- 6840-00F007530
===================== Product Identification ===================== Product ID:DURSBAN (R) 6R INSECTICIDAL CONCENTRATE MSDS Date:08/26/1981 FSC:6840 NIIN:00F007530 === Responsible Party === Company Name:DOW CHEMICAL U.S.A. City:MIDLAND State:MI ZIP:48640 Info Phone Num:(517) 636-4400 Emergency Phone Num:(517) 636-4400 CAGE:71954 === Contractor Identification === Company Name:DOW CHEMICAL U.S.A. Address:2020 DOW CENTER City:MIDLAND State:MI ZIP:48674 Phone:(517) 636-4400 CAGE:71954 Company Name:DOW CORNING CORP Address:3901 S SAGINAW RD Box:997 City:MIDLAND State:MI ZIP:48686-0997 Country:US Phone:517-496-6000/517-496-6315 CAGE:5D028 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORPYRIFOS (SARA III) CAS:2921-88-2 RTECS #:TF6300000 Fraction by Wt: 62.4% OSHA PEL:S, 0.2 MG/M3 ACGIH TLV:S, 0.2 MG/M3; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA III) CAS:1330-20-7 RTECS #:ZE2100000 Fraction by Wt: 37.6% OSHA PEL:100 PPM/150 STEL ACGIH TLV:100 PPM/150STEL;9192 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) 400-500 MG/KG Routes of Entry: Inhalation:NO Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYE: MAY CAUSE TRANSIENT IRRITATION BUT CORNEAL INJURY SHOULDN'T DEVELOP. SKIN: MAY CAUSE SLIGHT IRRITTION. PROLONGED/REPEATED CONTACT MAY CAUSE SLIGHT BURN/MAY BE ABSORBED THOROUGH SKIN, BUT MODERATE TO LOW TOXICITY. DRUNKENNESS & ANESTHETIC OR NARCOTIC EFFECT. MAY CAUSE CHEMICAL PNEUMONIA IF ASPIRATED INTO LUNGS. Explanation of Carcinogenicity:NONE Effects of Overexposure:CHOLINERGIC EFFECTS; SOLVENT VAPORS IF BREATHED MAY CAUSE IRRITATION, NAUSEA, & CENTRAL NERVOUS SYSTEM DEPRESSION. MAY PRODUCE ORGANO-PHOSPHORUS TYPE CHOLINESTERASE INHIBITION. ATROPINE BY INJECTION I S ANTIDOTE OF CHOICE. OXIMES MAY/MAY NOT BE THERAPEUTIC, BUT MUST NEVER BE USED IN PLACE OF ATROPINE. ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE WITH FLOWING WATER IMMEDIATELY & CONTINUOUSLY FOR 15 MIN. SKIN: WASH IN FLOWING WATER OR SHOWER. WASH CLOTHING BEFORE REUSE. INGESTION: DON'T INDUCE VOMITING. CALL PHYSICIAN. INHALATION : REMOVE TO FRESH AIR, CALL PHYSICIAN. IF RESPIRATION STOPS, GIVE MOUTH-TO-MOUTH RESUSCITATION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:112F Lower Limits:1% Upper Limits:6% Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMCIAL Fire Fighting Procedures:FOZ NOZZLE IS PREFERRED. USE POSITIVE-PRESSURE AIR SUPPLY. Unusual Fire/Explosion Hazard:TOXIC IRRITATING GASES MAY BE FORMED. RAPID DECOMPOSITION >160-200C. KEEP AWAY FROM HEAT, OPEN FLAME & SOURCES OF IGNITION. ================== Accidental Release Measures ================== Spill Release Procedures:SPILL BY DIKING TO KEEP OUT OF SEWERS OR WATERWAYS. ELIMINATE IGNITION SOURCES. ABSORB SPILLS WITH DRY MATERIAL SUCH AS SAND & SWEEP UP FOR DISPOSAL. FOR LARGE SPILLS, BARRICADE AREA & CONSULT MANUFAC TURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID INGESTION. AVOID SKIN & EYE CONTACT. AVOID BREATHING MIST OR VAPORS. KEEP AWAY FROM HEAT & OPEN FLAME. Other Precautions:HANDLE CONCENTRATE IN VENTILATED AREA. WASH THOROUGHLY AFTER HANDLING. DEPENDING ON DEGREE OF EXPOSURE OF PERSONNEL, CONSIDER MONITORING BLOOD CHOLINESTERASE LEVELS. KEEP AWAY FROM FOOD, FEEDSTUFFS & DOMESTIC WATER SUPPLIES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:APPROVED ORGANIC VAPOR-TYPE RESPIRATOR REQUIRED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. Ventilation:RECOMMEND CONTROL OF XYLENE TO SUGGESTED GUIDES. Protective Gloves:RUBBER Eye Protection:GOGGLES Other Protective Equipment:BOOTS, APRON DEPENDING UPON THE EXTENT & SEVERITY OF EXPOSURE LIKELY. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:290F Decomp Temp:Decomp Text:>160-200C Vapor Pres:40 Vapor Density:1 Spec Gravity:1.154 Solubility in Water:NONE Appearance and Odor:CLEAR LIQUID, MILD AROMATIC ODOR. Percent Volatiles by Volume:40% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASE. CONSULT MANUFACTURER FOR SPECIFIC GASES. Stability Condition to Avoid:AVOID HEAT >50C. WILL BURN UNDER FIRE CONDITIONS. Hazardous Decomposition Products:ON HEATING WILL DECOMPOSE TO FORM VOLATILE, FLAMMABLE, ODOROUS ORGANIC SULFIDES. Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT, OPEN FLAME & SOURCES OF IGNITION. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURY CLEAN-UP MATERIAL IN LOCATION AWAY FROM DOMESTIC WATER SUPPLIES, ACCORDING TO LOCAL, STATE, & FEDERAL REGULATIONS. CAUTION-CAN BE VERY TOXIC TO FISH AT 3 PPB LEVELS. KEEP OUT OF STREAMS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.