EASTMAN KODAK COMPANY -- 138 8701,PT A, KODAK EKTACOLOR RA BLEACH FIX AND REPLENISHER -- 6750-01-478-2940
===================== Product Identification ===================== Product ID:138 8701,PT A, KODAK EKTACOLOR RA BLEACH FIX AND REPLENISHER MSDS Date:05/01/2000 FSC:6750 NIIN:01-478-2940 Status Code:A Kit Part:Y === Responsible Party === Company Name:EASTMAN KODAK COMPANY Address:343 STATE STREET City:ROCHESTER State:NY ZIP:14650 Country:US Info Phone Num:716-722-5151/(800) 242-2424 Emergency Phone Num:716 722-5151 Preparer's Name:NOT PROVIDED CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:50. Maxumum % Wt:55. Other REC Limits:NOT PROVIDED Code:F Code:F Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 = Wt:40. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:SODIUM BISULFITE CAS:7631-90-5 RTECS #:VZ2000000 Minumum % Wt:5. Maxumum % Wt:10. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:5 MG/M3 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM BISULFITE CAS:10192-30-0 RTECS #:WT3595000 = Wt:1. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:AMMONIUM SULFITE CAS:10196-04-0 Minumum % Wt:1. Maxumum % Wt:5. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:NOT PROVIDED Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL HA S A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUAL S MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. INGESTION: MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTEN TION IF SYMPTOMS OCCUR. SKIN: WASH WITHSOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR THOROUGHLY CLEAN CONTAMINATED SHOES. INGESTION: DRIN K 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE. FLOOD WITH WATER. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT IN A NONCOMBUSTIBLE CONTAINER FOR PROMPT DISPOSAL. Neutralizing Agent:NOT PROVIDED ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION). DO NOT STORE OR SHIP TOGETHER WITH COMBUSTIBLE MATERIAL. STORE IN ORIG INAL CONTAINER. KEEP FROM CONTACT WITH OXIDIZING MATERIALS, HIGHLY OXYGENATED/ HALOGENATED SOLVENTS. Other Precautions:AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM COMBUSTIBLE MATERIAL. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: FULL-FACE ORGANIC VAPOR CARTRIDGE A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED. RESPIRATOR TYPE: ACID GAS. OBSERVE OSHA STANDARD 29 CFR 1910.134. Ventilation:USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. Protective Gloves:FOR PROLONGED OR REPEATED SKIN CONTACT: IMPERVIOUS GLOVES SHOULD BE WORN. Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER. Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE SKIN CONTACT. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:C3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:>100.C, 212.F Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:(68F):24 MBAR(18 MM HG) Vapor Density:0.6 Spec Gravity:1.24 pH:5.5 Viscosity:NOT PROVIDED Evaporation Rate & Reference:NOT PROVIDED Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID. ODOR: AMMONIA Percent Volatiles by Volume:50-55 WT Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG ACIDS, STRONG OXIDIZING AGENTS, COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS, BASES, SODIUM HYPOCHLORITE (BLEACH). CONTACT WITH BASE LIBERATES FLAMMABLE MATERIAL Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:AMMONIA, SULFUR DIOXIDE, CHLORAMINE, CARBON DIOXIDE, CARBON MONOXIDE, OXIDES OF NITROGEN, OXIDES OF SULFUR. =================== Toxicological Information =================== Toxicological Information:EFFECTS OF EXPOSURE: INHALATION: EXPECTED TO BE A LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED PERSONNEL. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR D IOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: CAUSES IRRITATION. SKIN: THIS MATERIAL HA S A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100. DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS READILY DEGRAD ABLE (>70%): YES (7 DAYS). POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 240. BOD5 (APPROXIMATE G/L): 200. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): NOT AVA ILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FR IDAY. ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: AMMONIUM THIOSULFATE, AMMONI UM BISULFITE; (AS CHEMICAL SOURCE OF AQUEOUS AMMONIA). Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.