BREAK-FREE INC -- BREAK-FREE PCL, NON-CHLORINATED LIQUID -- -
===================== Product Identification ===================== Product ID:BREAK-FREE PCL, NON-CHLORINATED LIQUID MSDS Date:07/17/1997 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:BREAK-FREE INC Address:13386 INTERNATIONAL PARKWAY City:JACKSONVILLE State:FL ZIP:32218 Country:US Info Phone Num:800-428-0588/ 904-741-5400 Emergency Phone Num:(800) 255-3924/ CHEM-TEL Resp. Party Other MSDS Num.:402-NC-00001-1-0-001 I-01A Preparer's Name:JAMES MERCER CAGE:65983 === Contractor Identification === Company Name:BREAK-FREE INC Address:13386 INTERNATIONAL PARKWAY Box:City:JACKSONVILLE State:FL ZIP:32218 Country:US Phone:800-428-0588/ 904-741-5400 CAGE:65983 ============= Composition/Information on Ingredients ============= Ingred Name:SOLVENT DEWAXED HEAVY PARAFFINIC OIL CAS:64742-65-0 RTECS #:PY8038500 = Wt:50.31 OSHA PEL:5 MG/M3 MIST ACGIH TLV:5 MG/M3 MIST Ingred Name:SYNTHETIC INHIBITORS AND LUBRICANT ADDITIVES (PROPRIETARY) = Wt:33.49 OSHA PEL:5 MG/M3 MIST ACGIH TLV:5 MG/M3 MIST Ingred Name:PTFE POWDER CAS:9002-84-0 RTECS #:KX4025000 = Wt:.7 OSHA PEL:5 MG/M3 DUST ACGIH TLV:5 MG/M3 DUST Ingred Name:PETROLEUM DISTILLATES, HYDROTREATED LIGHT CAS:64742-47-8 RTECS #:OA5504000 = Wt:7.66 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:2-ETHYLHEXYL ACETATE CAS:103-09-3 RTECS #:AH5600000 = Wt:7.84 ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO Health Hazards Acute and Chronic:WHILE EXPECTED TO BE NON-IRRITATING FROM THE SKIN, EYE, AND ORAL TESTING DONE, AS WITH ALL PETROLEUM PRODUCTS, PROLONGED AND REPEATED CONTACT WITH THE SKIN COULD CAUSE IRRITATION AND POSSIBLE DERMATI TIS. THE MINERAL OILS AND ADDITIVES COULD ALSO BE ABSORBED THROUGH ABRADED SKIN, BUT THE INFORMATION FROM DERMAL TOXICITY TESTS SUGGEST THAT NO ACUTE SYSTEMIC EFFECTS WOULD BE EXPECTED IN HEALTHY INDI VIDUALS. Explanation of Carcinogenicity:THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CARCINOGEN REQUIRED TO BE LISTED UNDER THE HAZARD COMMUNICATION STANDARD 29CFR 1910.1200 FROM THE NATIONAL TOXICOLOGY PROGRAM (NTP) OR THE INTERNATIONAL AGENC Y FOR RESEARH ON CANCER (IARC) SOURCES. Effects of Overexposure:INHALATION: RESPIRATORY IRRITATION & DISCOMFORT MAY BE EXPERIENCED IF MISTS OR MINERAL OILS OR RELATED MATERIALS ARE BREATHED AT AIR CONCENTRATIONS EXCEEDING RECOMMENDED EXPOSURE LEVELS. EXCESSIVE INH ALATION CAN CAUSE RESPIRATORY IRRITATION, CNS EFFECTS INCLUDING DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHES & POSSIBLE UNCONSCIOUSNESS. INGESTION: THE MIXTURE HAS A LOW LEVEL OF TOXICITY(LD50>5G/K G). SMALL AMOUNTS OF THE LIQUID ASPIRATED INTO THE RESPIRATORY SYSTEM DURING INGESTION OR VOMITING MAY CAUSE PULMONARY EDEMA OR BRONCHOPNEUMONIA. MINIMAL TOXICITY. (CONTD. SEE "TOXICOLOGICAL") ======================= First Aid Measures ======================= First Aid:FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES. EYE CONTACT: FLUSH WITH WATER FOR 15 MINUTES. IF SPILLED ON CLOTHING, REMOVE SOILED CLOTHING AND WASH SKIN WITH SOAP AND WATER. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE QUANTITIES OF WATER AND SEEK MEDICAL ATTENTION. IF INHALED, MOVE TO FRESH AIR. ANESTHETIC OR NARCOTIC EFFECTS COULD OCCUR FROM OVEREXPOSURE TO VAPORS, SO CALL A PHYSICIAN. IF AVAILABLE, GIVE OXYGEN. IF BREATHING STOPS, GIVE MOUTH-TO-MOUTH RESUSCITATION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=96.1C, 205.F Extinguishing Media:DRY CHEMICAL, CO2, OR FOAM. WATER OR FOAM MAY CAUSE FROTHING OF MATERIALS HEATED ABOVE 212F. CO2 CAN DISPLACE OXYGEN. USE CAUTION WHEN APPLYING CARBON DIOXIDE IN CONFINED SPACES. Fire Fighting Procedures:USE PROCEDURES FOR OIL AND SOLVENT MIXTURES. FIRE FIGHTERS SHOULD WEAR BUNKER GEAR, AN NIOSH APPROVED SCBA FOR FIRES BEYOND INCIPIENT STAGE, TO AVOID EXPOSURE TO DECOMPOSITION PRODUCTS (29CFR 1910.156 ). IN ADDITION, PROPER EYE AND SKIN PROTECTION SHOULD BE USED. USE WATER SPRAY TO DISPERSE VAPORS AND COOL EQUIPMENT. Unusual Fire/Explosion Hazard:THIS PRODUCT CONTAINS A HIGH PERCENTAGE OF SOLVENT (APPROXIMATELY 15.5 VOL.%). SOLVENT VAPORS ARE HEAVIER THAN AIR & CAN ACCUMULATE IN LOW, CONFINED, OR POORLY VENTILATED AREAS. THESE SOLVENT VAPORS M AY FLASH UPON CONTACT WITH FLAMES, SPARKS, OR HIGH INTENSITY HEAT SOURCES. ================== Accidental Release Measures ================== Spill Release Procedures:FOR SMALL SPILLS, VACUUM INTO WASTE CONTAINERS OR ABSORB WITH DRY SAND OR ABSORBENT CLOTH. FOR LARGE SPILLS EVACUATE AREA AND SHUT OFF POTENTIAL IGNITION SOURCES. ONLY PERSONNEL EQUIPPED WITH PROPER R ESPIRATORY AND SKIN/EYE PROTECTION SHOULD BE PERMITTED IN THE AREA. DIKE THE AREA TO CONTAIN THE SPILL. TAKE PRECAUTIONS TO PREVENT CONTAMINATION OF GROUND OR SURFACE WATERS. (CONTD. SEE "ECOLOGICAL") ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM OPEN FLAME OR OTHER IGNITION SOURCES. DO NOT STORE ABOVE 120F. MAINTAIN ADEQUATE VENTILATION AND KEEP FROM CHILDREN. Other Precautions:NOTE THAT VAPORS ARE HEAVIER THAN AIR AND CAN DISPLACE AIR IN LOW AREAS OR CONFINED SPACES SUCH AS PITS OR TANKS. DO NOT ENTER THOSE AREAS WHERE LARGE QUANTIITES OF VAPORS ARE SUSPECTED OR COLLECTING UNTIL EXCHANGING THE AIR OR USING SPECIAL BREATHING APPARATUS WITH AN OBSERVER PRESENT FOR POSSIBLE ASSISTANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED FOR NORMAL WORK SITUTATIONS WHERE ADEQUATE VENTILATION IS PROVIDED. USE NIOSH APPROVED SELF-CONTAINED POSITIVE PRESSURE RESPIRATORS FOR EMERGENCIES AND IN SITUATIONS WHERE AIR MAY BE DISP LACED BY VAPORS OR IN CONFINED AREAS WITH LOW AIR EXCHANGE RATES. FOLOW OSHA STD. 29CFR 1910.134. Ventilation:NO SPECIAL REQUIREMENTS. USE LOCAL EXHAUST AT FILLING ZONES AND WHERE LEAKAGE IS PROBABLE. USE MECHANICAL VENTILATION FOR STORAGE AREAS.(CONTD. SEE "SUPPL") Protective Gloves:POLYETHYLENE, NEOPRENE OR PVC PROTECTIVE GLOVES FOR PROLONGED SKIN CONTACT. Eye Protection:NONE REQUIRED FOR NORMAL CONDITIONS. CONTACT LENSES SHOULD NOT BE WORN. Other Protective Equipment:PROVIDE SAFETY SHOWER AND EYEWASH FOUNTAIN. PERSONAL PROTECTIVE CLOTHING AND USE OF EQUIPMENT MUST BE I/A/W 29CFR 1910.132 AND 29CFR 1910.133. WEAR SPLASH PROOF GOGGLES IF CHANCE FOR LIQUID CONTACT. Work Hygienic Practices:DO NOT SMOKE, EAT OR DRINK WHILE USING THIS PRODUCT. WASH HANDS WITH SOAP AND WATER BEFORE SMOKING, EATING, DRINKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. Supplemental Safety and Health (CONTD. FROM "VENTILATION") FOR GENERAL DILUTION OR LOCAL EXHAUST MAINTAIN ADEQUATE AIR EXCHANGE TO AVOID VAPOR BUILD-UP. ALL VENTILATION SHOULD BE DESIGNED IN ACCORDANCE WITH OSHA STD. 29 CFR 1910.94 . ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:=199.C, 390.2F B.P. Text:INITIAL Melt/Freeze Pt:<-40.C, -40.F M.P/F.P Text:POUR POINT Vapor Pres:<1.0 MMHG@ 20C(68F) Volatile Org Content %:15 Spec Gravity:0.89 Viscosity:45.45 CST @ 40C Evaporation Rate & Reference:<0.03 (N-BUTYL ACETATE=1) Solubility in Water:NIL Appearance and Odor:LIGHT AMBER COLOR; MILD ODOR. Percent Volatiles by Volume:15.5% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES AVOID STRONG OXIDIZING AGENTS. Stability Condition to Avoid:SOURCES OF IGNITION SUCH AS SPARKS, HOT SPOTS, WELDING, FLAMES, AND CIGARETTES. Hazardous Decomposition Products:OXIDES OF CARBON, SULFUR, NITROGEN,AND PTFE POWDER. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:(CONTD. FROM "SIGNS AND SYMPTOMS") SKIN CONTACT: POSSIBLE SLIGHT TO MADERATE REDNESS MAY OCCUR WITH EXTENDED DAILY EXPOSURE. NOT CLASSIFIED AS A PRIMARY SKIN IRRITANT OR CORROSIVE. EYE CONTACT: POSSI BLE TRANSIENT IRRITATION. NOT CLASSIFIED AS A PRIMARY IRRITANT. ===================== Ecological Information ===================== Ecological:(CONTD. FROM SPILL RELEASE) RECOVER WITH A WET VACUUM OR ABSORB SPILLED MATERIAL IN SAWDUST OR VERMICULITE AND SWEEP INTO CLOSED CONTANERS FOR DISPOSAL. AFTER ALL VISIBLE TRACES HAVE BEEN REMOVED, THO ROUGHLY WET VACUUM AREA AGAIN. DO NOT FLUSH INTO SEWER. ==================== Disposal Considerations ==================== Waste Disposal Methods:REPROCESS, INCINERATED, OR TREAT RECOVERED MATERIAL IN A PERMITTED FACILITY. TAKE CARE TO PREVENT ENVIRONMENTAL CONTAMINATION. DISPOSE OF CHEMICAL MATERIAL AND/OR THEIR CONTAINER I/A/W THE CLEAN AIR A CT, THE CLEAN WATER ACT, THE RESOURCE CONSERVATION AND RECOVERY ACT AS WELL AS FEDERAL, STATE, AND L OCAL LAWS AND REGULATIONS REGARDING DISPOSAL. =================== MSDS Transport Information =================== Transport Information:DOT CLASS: LIQUID, ORM-D. ===================== Regulatory Information ===================== SARA Title III Information:ALL SARA TITLE I I I MATERIALS HAVE BEEN REPORTED. ALL INGREDIENTS CONTAINED IN THIS FORMULA ARE LISTED ON THE TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL INVENTORY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.