BREAK-FREE INC -- BREAK-FREE PCL, NON-CHLORINATED LIQUID -- -
=====================  Product Identification  =====================

Product ID:BREAK-FREE PCL, NON-CHLORINATED LIQUID
MSDS Date:07/17/1997
FSC:NIIN:Submitter:D DG
Status Code:A
=== Responsible Party ===
Company Name:BREAK-FREE INC
Address:13386 INTERNATIONAL PARKWAY
City:JACKSONVILLE
State:FL
ZIP:32218
Country:US
Info Phone Num:800-428-0588/ 904-741-5400
Emergency Phone Num:(800) 255-3924/ CHEM-TEL
Resp. Party Other MSDS Num.:402-NC-00001-1-0-001 I-01A
Preparer's Name:JAMES MERCER
CAGE:65983
=== Contractor Identification ===
Company Name:BREAK-FREE INC
Address:13386 INTERNATIONAL PARKWAY
Box:City:JACKSONVILLE
State:FL
ZIP:32218
Country:US
Phone:800-428-0588/ 904-741-5400
CAGE:65983

=============  Composition/Information on Ingredients  =============

Ingred Name:SOLVENT DEWAXED HEAVY PARAFFINIC OIL
CAS:64742-65-0
RTECS #:PY8038500
= Wt:50.31
OSHA PEL:5 MG/M3 MIST
ACGIH TLV:5 MG/M3 MIST

Ingred Name:SYNTHETIC INHIBITORS AND LUBRICANT ADDITIVES (PROPRIETARY)
= Wt:33.49
OSHA PEL:5 MG/M3 MIST
ACGIH TLV:5 MG/M3 MIST

Ingred Name:PTFE POWDER
CAS:9002-84-0
RTECS #:KX4025000
= Wt:.7
OSHA PEL:5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST

Ingred Name:PETROLEUM DISTILLATES, HYDROTREATED LIGHT
CAS:64742-47-8
RTECS #:OA5504000
= Wt:7.66
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3

Ingred Name:2-ETHYLHEXYL ACETATE
CAS:103-09-3
RTECS #:AH5600000
= Wt:7.84

=====================  Hazards Identification  =====================

Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO
Health Hazards Acute and Chronic:WHILE EXPECTED TO BE NON-IRRITATING
    FROM THE SKIN, EYE, AND ORAL TESTING DONE, AS WITH ALL PETROLEUM
    PRODUCTS, PROLONGED AND REPEATED CONTACT  WITH THE SKIN COULD CAUSE
    IRRITATION AND POSSIBLE DERMATI TIS. THE MINERAL OILS AND ADDITIVES
    COULD ALSO BE ABSORBED THROUGH ABRADED SKIN, BUT THE INFORMATION
    FROM DERMAL TOXICITY TESTS SUGGEST THAT NO ACUTE SYSTEMIC EFFECTS
    WOULD BE EXPECTED IN HEALTHY INDI VIDUALS.
Explanation of Carcinogenicity:THIS MATERIAL IS NOT KNOWN TO CONTAIN
    ANY CARCINOGEN REQUIRED TO BE LISTED UNDER THE HAZARD COMMUNICATION
    STANDARD 29CFR 1910.1200 FROM THE NATIONAL TOXICOLOGY PROGRAM (NTP)
    OR THE INTERNATIONAL AGENC Y FOR RESEARH ON CANCER (IARC) SOURCES.
Effects of Overexposure:INHALATION: RESPIRATORY IRRITATION & DISCOMFORT
    MAY BE EXPERIENCED IF MISTS OR MINERAL OILS OR RELATED MATERIALS
    ARE BREATHED AT AIR CONCENTRATIONS EXCEEDING RECOMMENDED EXPOSURE
    LEVELS. EXCESSIVE INH ALATION CAN CAUSE RESPIRATORY IRRITATION, CNS
    EFFECTS INCLUDING DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHES &
    POSSIBLE UNCONSCIOUSNESS. INGESTION: THE MIXTURE HAS A LOW LEVEL OF
    TOXICITY(LD50>5G/K G). SMALL AMOUNTS OF THE LIQUID ASPIRATED INTO
    THE RESPIRATORY SYSTEM DURING INGESTION OR VOMITING MAY CAUSE
    PULMONARY EDEMA OR BRONCHOPNEUMONIA. MINIMAL TOXICITY.  (CONTD. SEE
    "TOXICOLOGICAL")

=======================  First Aid Measures  =======================

First Aid:FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES. EYE CONTACT: FLUSH
    WITH WATER	FOR 15 MINUTES. IF SPILLED ON CLOTHING, REMOVE SOILED
    CLOTHING AND WASH SKIN WITH SOAP AND WATER. LAUNDER CONTAMINATED
    CLOTHING  BEFORE REUSE. IF SWALLOWED, DO NOT INDUCE VOMITING. IF
    CONSCIOUS, DRINK LARGE QUANTITIES OF WATER AND SEEK MEDICAL
    ATTENTION. IF INHALED, MOVE TO FRESH AIR. ANESTHETIC OR NARCOTIC
    EFFECTS COULD OCCUR  FROM OVEREXPOSURE TO VAPORS, SO CALL A
    PHYSICIAN. IF AVAILABLE, GIVE OXYGEN. IF BREATHING STOPS, GIVE
    MOUTH-TO-MOUTH RESUSCITATION.

=====================  Fire Fighting Measures  =====================

Flash Point Method:PMCC
Flash Point:=96.1C, 205.F
Extinguishing Media:DRY CHEMICAL, CO2, OR FOAM. WATER OR FOAM MAY CAUSE
    FROTHING OF MATERIALS HEATED ABOVE 212F. CO2 CAN DISPLACE OXYGEN.
    USE CAUTION WHEN APPLYING CARBON DIOXIDE IN CONFINED SPACES.
Fire Fighting Procedures:USE PROCEDURES FOR OIL AND SOLVENT MIXTURES.
    FIRE FIGHTERS SHOULD WEAR BUNKER GEAR, AN NIOSH APPROVED SCBA FOR
    FIRES BEYOND INCIPIENT STAGE, TO AVOID EXPOSURE TO DECOMPOSITION
    PRODUCTS (29CFR 1910.156 ). IN ADDITION, PROPER EYE AND SKIN
    PROTECTION SHOULD BE USED. USE WATER SPRAY TO DISPERSE VAPORS AND
    COOL EQUIPMENT.
Unusual Fire/Explosion Hazard:THIS PRODUCT CONTAINS A HIGH PERCENTAGE
    OF SOLVENT (APPROXIMATELY 15.5 VOL.%). SOLVENT VAPORS ARE HEAVIER
    THAN AIR & CAN ACCUMULATE IN LOW, CONFINED, OR POORLY VENTILATED
    AREAS. THESE SOLVENT VAPORS M AY FLASH UPON CONTACT WITH FLAMES,
    SPARKS, OR HIGH INTENSITY HEAT SOURCES.

==================  Accidental Release Measures  ==================

Spill Release Procedures:FOR SMALL SPILLS, VACUUM INTO WASTE CONTAINERS
    OR ABSORB WITH DRY SAND OR ABSORBENT CLOTH. FOR LARGE SPILLS
    EVACUATE AREA AND SHUT OFF POTENTIAL IGNITION SOURCES. ONLY
    PERSONNEL EQUIPPED WITH PROPER R ESPIRATORY AND SKIN/EYE PROTECTION
    SHOULD BE PERMITTED IN THE AREA. DIKE THE AREA TO CONTAIN THE
    SPILL. TAKE PRECAUTIONS TO PREVENT CONTAMINATION OF GROUND OR
    SURFACE WATERS. (CONTD. SEE "ECOLOGICAL")

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP AWAY FROM OPEN FLAME OR OTHER
    IGNITION SOURCES. DO NOT STORE ABOVE 120F. MAINTAIN ADEQUATE
    VENTILATION AND KEEP FROM CHILDREN.
Other Precautions:NOTE THAT VAPORS ARE HEAVIER THAN AIR AND CAN
    DISPLACE AIR IN LOW AREAS OR CONFINED SPACES SUCH AS PITS OR TANKS.
    DO NOT ENTER THOSE AREAS WHERE LARGE QUANTIITES OF VAPORS ARE
    SUSPECTED OR COLLECTING  UNTIL EXCHANGING THE AIR OR USING SPECIAL
    BREATHING APPARATUS WITH AN OBSERVER PRESENT FOR POSSIBLE 
    ASSISTANCE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NOT REQUIRED FOR NORMAL WORK SITUTATIONS WHERE
    ADEQUATE VENTILATION IS PROVIDED. USE NIOSH APPROVED SELF-CONTAINED
    POSITIVE PRESSURE RESPIRATORS FOR EMERGENCIES AND IN SITUATIONS
    WHERE AIR MAY BE DISP LACED BY VAPORS OR IN CONFINED AREAS WITH LOW
    AIR EXCHANGE RATES. FOLOW OSHA STD. 29CFR 1910.134.
Ventilation:NO SPECIAL REQUIREMENTS. USE LOCAL EXHAUST AT FILLING ZONES
    AND WHERE LEAKAGE IS PROBABLE. USE MECHANICAL VENTILATION FOR
    STORAGE AREAS.(CONTD. SEE "SUPPL")
Protective Gloves:POLYETHYLENE, NEOPRENE OR PVC PROTECTIVE GLOVES FOR
    PROLONGED SKIN CONTACT.
Eye Protection:NONE REQUIRED FOR NORMAL CONDITIONS. CONTACT LENSES
    SHOULD NOT BE WORN.
Other Protective Equipment:PROVIDE SAFETY SHOWER AND EYEWASH FOUNTAIN. 
    PERSONAL PROTECTIVE CLOTHING AND USE OF EQUIPMENT MUST BE I/A/W
    29CFR 1910.132 AND 29CFR 1910.133. WEAR SPLASH PROOF GOGGLES IF
    CHANCE FOR LIQUID CONTACT.
Work Hygienic Practices:DO NOT SMOKE, EAT OR DRINK WHILE USING THIS
    PRODUCT. WASH HANDS WITH SOAP AND WATER BEFORE SMOKING, EATING,
    DRINKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING
    BEFORE REUSE.
Supplemental Safety and Health
(CONTD. FROM "VENTILATION") FOR GENERAL DILUTION OR LOCAL EXHAUST
    MAINTAIN ADEQUATE AIR EXCHANGE TO AVOID VAPOR BUILD-UP. ALL
    VENTILATION SHOULD BE DESIGNED IN ACCORDANCE WITH OSHA STD. 29 CFR
    1910.94 .

==================  Physical/Chemical Properties  ==================

HCC:V6
Boiling Pt:=199.C, 390.2F
B.P. Text:INITIAL
Melt/Freeze Pt:<-40.C, -40.F
M.P/F.P Text:POUR POINT
Vapor Pres:<1.0 MMHG@ 20C(68F)
Volatile Org Content %:15
Spec Gravity:0.89
Viscosity:45.45 CST @ 40C
Evaporation Rate & Reference:<0.03 (N-BUTYL ACETATE=1)
Solubility in Water:NIL
Appearance and Odor:LIGHT AMBER COLOR; MILD ODOR.
Percent Volatiles by Volume:15.5%

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:SOURCES OF IGNITION SUCH AS SPARKS, HOT
    SPOTS, WELDING, FLAMES, AND CIGARETTES.
Hazardous Decomposition Products:OXIDES OF CARBON, SULFUR, NITROGEN,AND
    PTFE POWDER.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

===================  Toxicological Information	===================

Toxicological Information:(CONTD. FROM "SIGNS AND SYMPTOMS") SKIN
    CONTACT: POSSIBLE SLIGHT TO MADERATE REDNESS MAY OCCUR WITH
    EXTENDED DAILY EXPOSURE.  NOT CLASSIFIED AS A PRIMARY SKIN IRRITANT
    OR CORROSIVE. EYE CONTACT: POSSI BLE TRANSIENT IRRITATION. NOT
    CLASSIFIED AS A PRIMARY IRRITANT.

=====================  Ecological Information  =====================

Ecological:(CONTD. FROM SPILL RELEASE) RECOVER WITH A WET VACUUM OR
    ABSORB SPILLED MATERIAL IN SAWDUST OR VERMICULITE AND SWEEP INTO
    CLOSED CONTANERS FOR DISPOSAL. AFTER ALL VISIBLE TRACES HAVE BEEN
    REMOVED, THO ROUGHLY WET VACUUM AREA AGAIN. DO NOT FLUSH INTO
    SEWER.

====================  Disposal Considerations  ====================

Waste Disposal Methods:REPROCESS, INCINERATED, OR TREAT RECOVERED
    MATERIAL IN A PERMITTED FACILITY. TAKE CARE TO PREVENT
    ENVIRONMENTAL CONTAMINATION. DISPOSE OF CHEMICAL MATERIAL AND/OR
    THEIR CONTAINER I/A/W THE CLEAN AIR A CT, THE CLEAN WATER ACT, THE
    RESOURCE CONSERVATION AND RECOVERY ACT AS WELL AS FEDERAL, STATE,
    AND L OCAL LAWS AND REGULATIONS REGARDING DISPOSAL.

===================  MSDS Transport Information  ===================

Transport Information:DOT CLASS: LIQUID, ORM-D.

=====================  Regulatory Information  =====================

SARA Title III Information:ALL SARA TITLE I I I MATERIALS HAVE BEEN
    REPORTED. ALL INGREDIENTS CONTAINED IN THIS FORMULA ARE LISTED ON
    THE TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL INVENTORY.

=======================  Other Information  =======================

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