CIBA-GEIGY CORP -- PRIMO -- 6840-00D003296
===================== Product Identification ===================== Product ID:PRIMO MSDS Date:10/13/1993 FSC:6840 NIIN:00D003296 === Responsible Party === Company Name:CIBA-GEIGY CORP Box:18300 City:GREENSBORO State:NC ZIP:27419 Country:US Info Phone Num:800-888-8372 Emergency Phone Num:800-888-8372 800-424-9300(CHEMTREC) Preparer's Name:ENV SAFETY + COMPLAINCE CAGE:8K295 === Contractor Identification === Company Name:CIBA-GEIGY CORP Box:City:GREENSBORO State:NC ZIP:27419 Country:US Phone:800-888-8372 CAGE:8K295 ============= Composition/Information on Ingredients ============= Ingred Name:NAPHTHALENE (SARA III) CAS:91-20-3 RTECS #:QJ0525000 Fraction by Wt: 6.6% Other REC Limits:NONE RECOMMENDED OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL; 9394 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:PETROLEUM SOLVENT Other REC Limits:NONE RECOMMENDED Ingred Name:SURFACE ACTIVE INGREDIENT Other REC Limits:NONE RECOMMENDED Ingred Name:MINERAL OIL (EXPOSURE REGULATED AS 'OIL MIST') CAS:8012-95-1 RTECS #:PY8030000 Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 (MIST); 9394 Ingred Name:CYCLOHEXANECARBOXYLIC ACID,4-(CYCLOPROPYLHYDROXYMETHYLENE)-3,5-DIOXO-ETHYL ESTER CAS:95266-40-3 RTECS #:GU8473500 Other REC Limits:NONE RECOMMENDED Ingred Name:EMULSIFIERS Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 5130MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES:MAY CAUSE IRRITATION.SKIN:MAY CAUSE IRRITATION AND DEFATTING.INGEST:MAY CAUSE GI TRACT IRRITATION AND CNS DEPRESSION.MAY CAUSE LUNG DAMAGE IF VOMITED AFTER INGESTING.INHAL:MAY CAUSE RESPIRATORY I RRITATION AND CNS DEPRESSION.CHRONIC:NAPHTHALENE CAN CAUSE DAMAGE TO LIVER,KIDNEY AND BLOOD FORMING ORGANS AND CATARACTS Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA. Effects of Overexposure:INHAL:DIZZINESS,HEADACHE,ANESTHETIC EFFECT.SKIN:DEAFTTING EFFECT MAY RESULT IN PHOTOSENSITIZATION. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING CONDITIONS OF THE EYE,SKIN,LIVER,KIDNEY RESPIRATORY OR BLOOD FORMING ORGANS MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND WATER,INCLUDING HAIR AND UNDER FINGERNAILS.EYES:FLUSH WITH WATER FOR 15 MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE PLENTY OF WATER. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:125F,52C Lower Limits:0.8 Upper Limits:7.0 Extinguishing Media:DRY CHEMCIAL,FOAM,CARBON DIOXIDE. Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT. Unusual Fire/Explosion Hazard:PREVENT USE OF BUILDING AND EQUIPMENT UNTIL IT HAS BEEN DECONTAMINATED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER RESPIRATORY AND PROTECTIVE EQUIPMENT.SHUT OFF LEAK IF SAFE.DIKE.SOAK UP WITH A NON-COMBUSTIBLE INERT ABSORBANT(CLAY,SAND);PLACE IN PROPER CONTAINER FOR DISPOSAL.WASH SPILL AREA WITH A DETER GENT TO REMOVE SLIPPINESS.KEEP OUT OF WATERWAYS. Neutralizing Agent:NONE ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.KEEP AWAY FROM FOOD. Other Precautions:FOLLOW LABEL DIRECTIONS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN ENCLOSED SPACES USE A NIOSH/MSHA APPROVED RESPIRATOR FOR PESTICIDE VAPOR. Ventilation:FOR OUTDOOR USE ONLY. Protective Gloves:RUBBER Eye Protection:CHEMICAL GOGGLES. Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL EYE WASH STATION AND SAFETY SHOWER. Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK AREA. Supplemental Safety and Health NONE ================== Physical/Chemical Properties ================== HCC:C3 Vapor Pres:1.6E-3 Spec Gravity:0.994 pH:3-5 Solubility in Water:MODERATE;2.7% Appearance and Odor:LIQUID;AMBER;AROMATIC ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES MANUFACTURER STATES NONE KNOWN. Stability Condition to Avoid:MANUFACTURER STATES NONE KNOWN. Hazardous Decomposition Products:MANUFACTURER STATES NONE KNOWN. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.FOR SPECIFIC INFORMATION,CALL CIB-GEIGY AT 800-334-9481. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.