EASTMAN KODAK COMPANY -- 169 1757,PT B,TONING BATH,KODAK SEPIA TONER -- 6750-00-110-8067
===================== Product Identification ===================== Product ID:169 1757,PT B,TONING BATH,KODAK SEPIA TONER MSDS Date:02/28/2000 FSC:6750 NIIN:00-110-8067 Status Code:A Kit Part:Y === Responsible Party === Company Name:EASTMAN KODAK COMPANY Address:343 STATE STREET City:ROCHESTER State:NY ZIP:14650 Country:US Info Phone Num:716-722-5151/(800) 242-2424 Emergency Phone Num:716 722-5151 Preparer's Name:NOT PROVIDED CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM SULFIDE CAS:1313-82-2 RTECS #:WE1905000 Minumum % Wt:60. Maxumum % Wt:65. Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:35. Maxumum % Wt:40. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD-50 (RAT): 100-200 MG/KG Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EFFECTS OF EXPOSURE: INHALATION: HARMFUL IF INHALED. AIRBORNE DUST IRRITATING. IF HYDROGEN SULFIDE GAS IS LIBERATED DUE TO CONTACT WITH ACID, IT MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, CONFUSION, WEAKN ESS, UNCONSCIOUSNESS, CONVULSIONS AND DEATH. EYES: CAUSES BURNS. SKIN: CAUSES BURNS. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF SWALLOWED. IF FREE GASTRIC ACID ITY IS HIGH, HYDROGEN SULFIDE IS LIBERATED IN THE STOMACH AND MAY CAUSE SYSTEMIC TOXIC EFFECTS SUCH AS VOMITING, RESPIRATORY DEPRESSION, TREMORS, CONVULSIONS AND DEATH. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: AIRBORNE DUST IRRITATING. IF HYDROGEN SULFIDE GAS IS LIBERATED DUE TO CONTACT WITH ACID, IT MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, CONFUSION, WEAKNESS, UNCONSCIOUSNESS, CONVULSIONS AND DEA TH. EYES: CAUSES BURNS. SKIN: CAUSES BURNS. INGESTION: MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF SWALLOWED. IF FREE GASTRIC ACIDITY IS HIGH, HYDROGEN SULFIDE IS LIBERATED IN THE STOMACH AND MAY CAUSE SYSTEMIC TOXIC EFFECTS SUCH AS VOMITING, RESPIRATORY DEPRESSION, TREMORS, CONVULSIONS AND DEATH. Medical Cond Aggravated by Exposure:NOT PROVIDED ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. GET MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WA TER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. INGESTION: DO NOT INDUCE VOMITING. GIVE VICTIM A GLAS S OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:WATER SPRAY, CARBON DIOXIDE (CO2), DRY CHEMICAL Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. ================== Accidental Release Measures ================== Spill Release Procedures:COLLECT UP AND PUT IN A SUITABLE CONTAINER. AVOID GENERATION OF DUST. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. Neutralizing Agent:NOT PROVIDED ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. POWDERED MATERIAL MAY FORM EXPLOSIVE DUST-AIR MIXTURES. MINIMIZE DUST GENERATION AND ACCUMULATION. KEEP AWAY FROM SOURCES OF IGNITION. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. Other Precautions:AVOID BREATHING DUST. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. REFER TO NFPA PAMPHLET NO. 654, " PREVENTION OF FIRE AND DUST EXPLOSIONS IN THE CHEMICAL, DYE, PHARMACEUTICAL, AND PLASTICS INDUSTRIES ." ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE CONCENTRATIONS TO AN ACCEPTABLE LEVEL, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: DUST. A FULL-FACE POSITIVE-PRESSURE AIR-SUPPLIED RESPIRATO R MUST BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE RELEASED OR HAVE BEEN RELEASED. OBSERVE OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A FACE SHIELD. Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES Work Hygienic Practices:NOT PROVIDED Supplemental Safety and Health USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P =NOT PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT ESTABLISHED. ================== Physical/Chemical Properties ================== HCC:B1 NRC/State Lic Num:NOT RELEVANT Boiling Pt:=145.C, 293.F Melt/Freeze Pt:=90.6C, 195.F Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:NEGLIGIBLE Spec Gravity:1.69 Solubility in Water:APPRECIABLE Appearance and Odor:LIGHT YELLOW SOLID (FLAKE). ODOR: PUNGENT Percent Volatiles by Volume:NEGLIGIBLE Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG ACIDS. CONTACT WITH ACID LIBERATES FLAMMABLE MATERIAL, POISONOUS GAS. Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:HYDROGEN SULFIDE, OXIDES OF SULFUR. =================== Toxicological Information =================== Toxicological Information:EFFECTS OF EXPOSURE: INHALATION: HARMFUL IF INHALED. AIRBORNE DUST IRRITATING. IF HYDROGEN SULFIDE GAS IS LIBERATED DUE TO CONTACT WITH ACID, IT MAY CAUSE HEADACHE, NAUSEA, DIZZINESS, CONFUSION, WEAKN ESS, UNCONSCIOUSNESS, CONVULSIONS AND DEATH. EYES: CAUSES BURNS. SKIN: CAUSES BURNS. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT IF SWALLOWED. IF FREE GASTRIC ACID ITY IS HIGH, HYDROGEN SULFIDE IS LIBERATED IN THE STOMACH AND MAY CAUSE SYSTEMIC TOXIC EFFECTS SUCH AS VOMITING, RESPIRATORY DEPRESSION, TREMORS, CONVULSIONS AND DEATH. ORAL LD-50 (RAT): 100-200 MG/K G. DERMAL LD-50: < 340 MG/KG ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: 1-10. DAPHNID EC50 MG/L: 10-100. ALGAL IC50 MG/L: >100. ORGANICS READILY DEGR ADABLE (>70%): NOT APPLICABLE. POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): NOT PROVIDED. BOD5 (APPROXIMATE G/L): NOT AVAILABLE. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISM S EC50 (MG/L): NOT AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED. CONTRACT WIT H A LICENSED CHEMICAL DISPOSAL AGENCY. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY . ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: NONE Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.