DOW ELANCO, A JOINT VENTURE -- DURSBAN 2 E INSECTICIDE,01147 -- 6840-00D001801
===================== Product Identification ===================== Product ID:DURSBAN 2 E INSECTICIDE,01147 MSDS Date:11/29/1993 FSC:6840 NIIN:00D001801 === Responsible Party === Company Name:DOW ELANCO, A JOINT VENTURE Address:QUAD IV, 9002 PURDUE RD City:INDIANAPOLIS State:IN ZIP:46268 Country:US Info Phone Num:800-362-6776 Emergency Phone Num:517-636-4400 CAGE:0TNR0 === Contractor Identification === Company Name:DOW ELANCO Address:QUAD IV, 9002 PURDUE RD Box:City:INDIANAPOLIS State:IN ZIP:46268-1189 Country:US Phone:517-636-4400 CAGE:0TNR0 ============= Composition/Information on Ingredients ============= Ingred Name:CHLORPYRIFOS (CERCLA) CAS:2921-88-2 RTECS #:TF6300000 Fraction by Wt: 24.1% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 0.2 MG/M3 ACGIH TLV:S, 0.2 MG/M3; 9495 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:NAPHTHA, LIGHT AROMATIC (SOLVENT NAPHTHA)/PETROLEUM DISTILLATE, AROMATIC HYDROCARBON CAS:64742-95-6 RTECS #:WF3400000 Other REC Limits:NONE RECOMMENDED OSHA PEL:5 MG/M3 AS OIL MIST ACGIH TLV:5 MG/M3 AS OIL MIST Ingred Name:XYLENES (O-,M-,P- ISOMERS) (SARA 313) (CERCLA) CAS:1330-20-7 RTECS #:ZE2100000 Other REC Limits:NONE RECOMMENDED OSHA PEL:100 PPM ACGIH TLV:100 PPM/150STEL;9495 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA 313) CAS:95-63-6 RTECS #:DC3325000 Other REC Limits:NONE RECOMMENDED OSHA PEL:25 PPM ACGIH TLV:25 PPM; 9495 Ingred Name:CUMENE (SARA 313) (CERCLA) CAS:98-82-8 RTECS #:GR8575000 Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 50 PPM ACGIH TLV:S, 50 PPM; 9495 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:ETHYLTOLUENE CAS:25550-14-5 Other REC Limits:NONE RECOMMENDED Ingred Name:EMULSIFIERS, PROPRIETARY Other REC Limits:NONE RECOMMENDED ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50(ORAL RAT)MALE 1173;FEMALE:766 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, LUNG, LIVER, KIDNEY. ACUTE- MAY CAUSE CORNEAL INJURY. PROLONGED SKIN CONTACT MAY CAUSE IRRITATION. CAN BE ABSORBED THROUGH SKIN. INGESTION OF LARGE AMOUNTS MAY CAUSE INJU RY. ASPIRATION HAZARD. INHALATION MAY CAUSE IRRITATION & CNS DEPRESSION. CHRONIC- DERMATITIS, KIDNEY & LIVER EFFECTS. Explanation of Carcinogenicity:NONE Effects of Overexposure:ORGANOPHOSPHATE TYPE CHOLINESTERASE INHIBITION, HEADACHE, DIZZINESS, INCOORDINATION, MUSCLE TWITCHING TREMORS, NAUSEA, ABDOMINAL CRAMPS, DIARRHEA, SWEAT, PINPOINT PUPILS, BLURRED VISION, SALIVATION, T EARING, TIGHT CHEST, CONVULSION, DROWSINESS, UNCONSCIOUSNESS Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, LIVER, KIDNEYS, BONE MARROW, BLOOD CELLS, CNS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ATTENTION. EYE/SKIN:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED. ORAL:DON'T INDUCE VOMITING. NOTE TO PHYSICIAN:IF LAVAGE I S PERFORMED, SUGGEST ENDOTRACHEAL AND/OR ESOPHAGEAL CONTROL. CHLORPYRIFOS IS CHOLINESTERASE INHIBITOR. ATROPINE(IV) IS ANTIDOTE OF CHOICE. TREATMENT BASED ON JUDGMENT OF DOCTOR IN RESPONSE OF PATIENT. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:102F,39C Lower Limits:1% XYLENE Upper Limits:6% XYLENE Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM/DRY CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:TOXIC AND IRRITATING GASES MAY BE FORMED. RAPID DECOMPOSITION ABOVE 320-392F (160-200C). VIOLENT RUPTURE OF CONTAINERS FROM OVER-PRESSURIZATION MAY OCCUR. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES OF IGNITION. VENTILATE AREA. ABSORB SPILLS WITH ABSORBENT MATERIAL SUCH AS DRY SAND, ZORBALL OR DIRT. KEEP OUT OF WATERWAYS AND SEWERS. WASH SPILL AREA THO ROUGHLY AFTER PICKUP IS COMPLETE. Neutralizing Agent:NOT RELEVENT ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA, IN TIGHTLY CLOSED CONTAINERS, AWAY FROM FLAMES & INCOMPATIBLES. KEEP AWAY FROM FOOD, FEEDSTUFFS AND WATER SUPPLIES. Other Precautions:SEE LABEL. AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. KEEP OUT OF REACH OF CHILDREN. DO NOT SWALLOW. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN RESPIRATORY PROTECTION IS REQUIRED USE A NIOSH-APPROVED AIR-PURIFYING RESPIRATOR. FOR EMERGENCIES USE APPROVED POSITIVE PRESSURE SELF CONTAINED BREATHING APPARATUS. Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S). Protective Gloves:NITRILE Eye Protection:CHEMICAL GOGGLES/FULL-FACE RESPIRATOR Other Protective Equipment:WEAR IMPERVIOUS CLOTHING, BOOTS, APRON OR FULL-BODY SUIT. PROVIDE SAFETY SHOWER AND EYE WASH FOUNTAIN. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN. DEPENDING ON DEGREE OF EXPOSURE OF PERSONNEL, CONSIDER MONITORING BLOOD CHOLINESTERASE LEVELS. EPA REGISTRATION NUMBER: 62719-55. ================== Physical/Chemical Properties ================== HCC:F5 NRC/State Lic Num:NOT RELEVENT Boiling Pt:B.P. Text:320F,160C Decomp Temp:Decomp Text:320F - 392F Vapor Pres:< 10 @ 77F Spec Gravity:0.98 Solubility in Water:EMULSIFIABLE Appearance and Odor:YELLOW LIQUID; MERCAPTAN-TYPE ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALINE MATERIALS Stability Condition to Avoid:HEAT >122F(50C). CHLORPYRIFOS UNDERGOES EXOTHERMIC DECOMP. AT 266F WHICH CAN LEAD TO HIGHER TEMPS & VIOLENT DECOMP. Hazardous Decomposition Products:CARBON MONOXIDE & DIOXIDE, HYDROGEN CHLORIDE, ETHYL SULFIDE, DIETHYL SULFIDES AND NITROGEN OXIDES CAN BE FORMED. ==================== Disposal Considerations ==================== Waste Disposal Methods:PESTICIDE WASTES ARE TOXIC. DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. REPORTABLE QUANTITY FOR CHLORPYRIFOS IS 1 POUND. IMPROPER DISPOSAL OF EXCESS PESTICIDE, SPRAY MIXTUR E, OR RINSATE IS A VIOLATION OF FEDERALLAW. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.