EAGLE-PICHER MINERALS INC -- CELATOM SP -- 9390-00N087925
===================== Product Identification ===================== Product ID:CELATOM SP MSDS Date:11/01/1997 FSC:9390 NIIN:00N087925 === Responsible Party === Company Name:EAGLE-PICHER MINERALS INC Address:8110 PLUMAS City:RENO State:NV ZIP:89508 Country:US Info Phone Num:702-824-7800 Emergency Phone Num:702-824-7800 Preparer's Name:PATRICK T FLYNN JR CAGE:EAGLE === Contractor Identification === Company Name:EAGLE-PICHER INDUSTRIES INC Address:6110 PLUMES Box:City:RENO State:NV ZIP:89509 Country:US Phone:702-824-7650 CAGE:0PXU6 Company Name:EAGLE-PICHER MINERALS, INC. Address:8110 PLUMAS Box:12130 City:RENO State:NV ZIP:89510 Country:US Phone:702-322-3331 CAGE:EAGLE ============= Composition/Information on Ingredients ============= Ingred Name:DIATOMACEOUS EARTH, FLUX-CALCINED CAS:68855-54-9 Fraction by Wt: 100% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE CAS:14464-46-1 RTECS #:VV7325000 Fraction by Wt: 35-50% OSHA PEL:SEE TABLE Z-3 ACGIH TLV:0.05 MG/M3 RDUST Ingred Name:SUPDAT: TO NATL & REGIONAL POPULATIONS. THIS IS REDUCTION IN LEVELS RPTD IN 1992 RPT (SMR=2.89 FOR NMRD & SMR= (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: 1.43 FOR LUNG CANCER). AS NOTED IN 1982 STUDY, RELATIVELY INTENSE EXPOS TO CRYSTALLINE SILICA THAT (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: OCCURRED BEFORE 1950'S WERE PROBABLY MOST IMPORTANT CONTRIBUTORS TO EXCESSES IN NMRD & LUNG CANCER. 1988 (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: RPT CONTINUES TO SUPPORT CONCLUSION THAT RECENT IMPROVEMENTS IN DUST CTL IN INDUSTRY APPEAR TO HAVE (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: ABRADED ANY EXCESS RISK OF SILICOSIS/LUNG CANCER IN TODAY'S WORK ENVIRONMENT. SOON TO BE PUBLISHED (1987) (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: RADIOGRAPHIC STUDY ALSO APPEARS TO SUPPORT FACT THAT CURRENT OCCUP EXPOS & OCCUP EXPOS LIMITS ARE ADEQ TO (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: PVNT EXCESS RISKS OF DEVELOPING SILICOSIS FROM DIATOMACEOUS EARTH. MORE DETAILED RPT DISCUSSING IARC (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: CLASSIFICATION & DIATOMITE WORKER STUDIES IS AVAIL ON REQUEST. UPPER RESP IRRITANT-MAY CAUSE COUGH/THROAT(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: IRRIT. CHRONIC: INHAL OF CRYSTALLINE SILICA DUST IN EXCESS OF TLV REC BY ACGIH/IN EXCESS OF LIMIT PEL (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: ESTABLISHED BY OSHA OVER EXTENDED NUMBER OF YRS MAY CAUSE SILICOSIS, PROGRESSIVE SOMETIMES FATAL LUNG (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: DISEASES. ALTHOUGH SILICOSIS IS NON-CANCEROUS LUNG DISEASE, 1992 STUDY CONDUCTED BY UNIVERSITY OF (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: WASHINGTON ON CERTAIN DIATOMITE WORKERS, & 1996 FOLLOW-UP TO THIS STUDY, INDICATES THAT EXPOS TO HIGH (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: CONCS OF CRYSTALLINE SILICA FOR MANY YRS MAY INCR POTNTL RISK OF DEVELOPING LUNG CANCER. 1996 FOLLOW-UP (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: STUDY CONTINUES TO SUPPORT FINDING OF 1992 STUDY IN THAT FOR THOSE WORKERS HIRED SINCE 1960, NO INCR IN (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: LUNG CANCER MORTALITY RISK WAS FOUND. CONSEQUENTLY, MAINTAINANCE OF CRYSTALLINE SILICA DUST CONC @/BELOW(ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: LEVELS SPECIFIED BY OCCUP STDS SETTING AGENCIES WILL MINIMIZE, IF NOT ELIM, ANY POTNTL EXCESS RISK OF (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: NMRD OR LUNG CANCER. TARGET ORGANS: LUNGS. RTECS #:9999999ZZ Ingred Name:RESP PROT: CNTNG DUSTS. IF DUST CONC IS >10 TIMES & <100 TIMES PEL USE NIOSH APPRVD FULL FACEPIECE RESP WITH (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: REPLACABLE DUST FILTER; IF >100 & <200 TIMES PEL USE NIOSH APPRVD POWER AIR-PURIFYING (POS PRESS) RESP(ING 22) RTECS #:9999999ZZ Ingred Name:ING 21: W/REPLACABLE FILTER; IF >200 TIMES PEL USE NIOSH APPRVD TYPE C, SUPPLIED-AIR RESP, CONTINUOUS FLOW TYPE(ING 23) RTECS #:9999999ZZ Ingred Name:ING 22: (POSITIVE PRESSURE), W/FULL FACEPIECE, HOOD, OR HELMET. RTECS #:9999999ZZ Ingred Name:VENT: OR SIMILAR PUBLICATIONS FOR DESIGN OF VENTILATION SYSTEMS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:ACUTE: FLUX-CALCINED DIATOMACEOUS EARTH(KIESELGUHR) CNTNS CRYSTALLINE SILICA WHICH IS KNOWN CAUSE OF SILICOSIS, PROGRESSIVE, SOMETIMES FATAL, LUNG DISEASE. IN 1997 MONO (VOL 68, "SILICA, SOME SILICATE S, COAL DUST & PARA- ARAMID FIBRIS"), THE IARC HAS CLASSIFIED "INHALED CRYSTALLINE SILICA FROM OCCUP (EFTS OF OVEREXP) Explanation of Carcinogenicity:SILICA, CRYSTALLINE-CRISTOBALITE: IARC MONO, VOL 68, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCIN, 1994: ANTIC (SUPDAT) Effects of Overexposure:HLTH HAZ: SOURCES" IN GROUP 1 AS SUBSTANCE "CARCIN TO HUMANS." IN MAKING OVERALL EVAL, IARC WORKING GROUP NOTED THAT CARCINOGENICITY IN HUMANS WAS NOT DETECTED IN ALL INDUST CIRCUMSTANCES STUDIED. ALT HOUGH RECENT IARC DETERMINATION WAS, INPART, BASED ON 1982 STUDY OF DIATOMITE WORKERS, 1986 FOLLOW-UP WHICH (SUPDAT) Medical Cond Aggravated by Exposure:PRE-EXISTING DISEASES OF THE UPPER RESPIRATORY TRACT AND LUNG SUCH AS BRONCHITIS, EMPHYSEMA, AND ASTHMA. ======================= First Aid Measures ======================= First Aid:SKIN: USE MOISTURE RENEWING LOTIONS IF DRYNESS OCCURS. EYE: WASH W/GENEROUS QTYS OF WATER FOR @ LST 15 MINS. CONSULT PHYS IF IRRIT PERSISTS. INHAL: REMOVE TO FRESH AIR. INGEST: DRINK GENEROUS AMOUNTS OF WATER TO REDUCE BULK & DRYING EFFECTS. ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT APPLICABLE. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:NOT APPLICABLE. USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:VACUUM CLEAN SPILLAGE, WET SWEEP OR WASH AWAY. AVOID CREATING DUST. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A DRY PLACE TO MAINTAIN PRODUCT QUALITY. AVOID CREATING. Other Precautions:REPAIR OR PROPERLY DISPOSE OF BROKEN BAGS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH APPRVD RESPS FOR PROT AGAINST PNEUMOCONIOSIS PRODUCING DUSTS REC WHEN DUST IS PRESENT. IF DUST CONC IS <10 TIMES PEL, USE NIOSH APPRVD QUARTER/HALF MASK RESP W/REPLACEMENT DUST FILTER/SINGLE USE DUST RESP APPRVD FOR SILICA(ING 20) Ventilation:ENGINEERING CTLS(E.G., VENT, ENCLOSED PROCESS); LOC-CTL W/REC TLV/PEL. REFER TO ACGIH PUBLICATION "INDUST VENT"(ING 24) Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 10 (10% SLURRY). EXPLAN OF CARCIN: TO BE CARCIN. EFTS OF OVEREXP: WAS ISSUED BY UNIVERSITY OF WASHINGTON & TULANE UNIVERSITY WAS NOT AVAIL TO WORKING GROUP. THE FOLLOW-UP STUDY RPTD STANDARIZED MO RTALITY RATIO (SMR) OF 2.01 FOR NON-MALIGNANT RESP DISEASE(NMRD) & AN SMR OF 1.29 FOR LUNG CANCER WHEN COMBINED (ING 3) ================== Physical/Chemical Properties ================== Spec Gravity:2.0 pH:SUPDAT Evaporation Rate & Reference:NOT KNOWN Solubility in Water:<2% Appearance and Odor:SOLID LIGHT PINK TO WHITE POWDER, ODORLESS. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES HYDROFLUORIC ACID. PRODUCTS CONTAINING SILICA MAY REACT VIOLENTLY WITH HYDROFLUORIC ACID. Stability Condition to Avoid:NOT APPLICABLE. Hazardous Decomposition Products:NOT APPLICABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:NON-BIODEGRADABLE. USE SOLID WASTE DISP COMMON TO LANDFILL TYPE OPERATIONS/IN SLURRY TO SUMPS, NOT CONSIDERED HAZARDOUS WASTE UNDER RCRA(40CFR PART 261). DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS . Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.