QUANTUM CHEMICAL CO -- 200 PROOF PUNCTILIOUS, DEHYDRATED (SUPDAT) -- 6810-00N011353
===================== Product Identification ===================== Product ID:200 PROOF PUNCTILIOUS, DEHYDRATED (SUPDAT) MSDS Date:03/10/1994 FSC:6810 NIIN:00N011353 === Responsible Party === Company Name:QUANTUM CHEMICAL CO Address:11500 NORTHLAKE DR Box:429550 City:CINCINNATI State:OH ZIP:45249 Country:US Info Phone Num:800-543-5900;513-530-4051 Emergency Phone Num:713-479-2873;800-424-9300(CHEMTREC) Preparer's Name:HSE CAGE:78918 === Contractor Identification === Company Name:QUANTUM CHEMICAL CORPORATION USI DIVISION Address:11500 NORTHLAKE DRIVE Box:429550 City:CINCINNATI State:OH ZIP:45249 Country:US Phone:713-479-2873/800-424-9300(CHEMTREC) CAGE:78918 ============= Composition/Information on Ingredients ============= Ingred Name:ING 9:CNTNR MUST BE BONDED TO RECEIVING CNTNR & GROUNDED TO AVOID STATIC DISCHARGES. NEVER USE PRESS TO EMPTY. (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10:REPLACE CLOSURE SECURELY AFTER EACH OPENING. KEEP PACKAGED MATL OUT OF SUN & AWAY FROM HEAT. REMOVE (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11:CLOSURE CAREFULLY; INTERNAL PRESS MAY BE PRESENT. KEEP CLOSURE UP TO PVNT LEAKAGE. CNTNRS HAZ WHEN (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12:EMPTIED. SINCE EMPTIED CNTNRS RETAIN RESIDUAL PROD (VAP/LIQ), ALL PRECS DESCRIBED IN MSDS MUST BE (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13:OBSERVED. FOR INDUST USE ONLY. NOT FOR HOUSEHOLD USE. NOT INTENDED/PERMITTED FOR DRINKING BEVERAGE PURPOSES. RTECS #:9999999ZZ Ingred Name:VENT:NOT LIMITED TO ENCLOSURES, LOCAL VENTILATION & DILUTION VENTILATION. RTECS #:9999999ZZ Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: 100% OSHA PEL:1000 PPM ACGIH TLV:1000 PPM Ingred Name:SUPDAT:CAVITY, PHARYNX, LARYNX, ESOPHAGUS, & LIVER. INGEST OF ALCOHOLIC BEVERAGES BY PREGNANT WOMEN IS ASSOC W/ (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2:"FETAL ALCOHOL SYNDROME" IN OFFSPRING. EYE:ETHYL ALCOHOL, EITHER AS LIQ/VAP, MAY CAUSE EYE IRRIT. SKIN: (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3:ETHYL ALCOHOL MAY CAUSE IRRIT & DEFAT OF SKIN UPON PROLONGED CONTACT. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:NOT PERMIT VICTIM TO RUB EYES. GET MED ATTN IMMED!. INHAL:IMMED REMOVE VICTIM TO FRESH AIR. IF (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5:VICTIM HAS STOPPED BRTHG, GIVE ARTF RESP, PREFERABLY MOUTH-TO-MOUTH. GET MED ATTN IMMED. RTECS #:9999999ZZ Ingred Name:OTHER PREC:CAREFUL LEAKAGE INSPECTION SHOULD BE DONE. AUTOMATIC SPRINKLER SYS SHOULD BE PROVIDED. ISOLATE FROM (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7:OXIDIZERS, CHEMS CAPABLE OF SPONT HEATING, MATLS REACTING W/AIR/MOISTURE TO LIBERATE HEAT, IGNIT SOURCES (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:& EXPLOSIVES. CONSULT LOCAL FIRE CODES FOR ADDNL STOR INFO. WHEN CONTENTS ARE BEING TRANSFERRED, METALLIC (ING 10) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL,RAT) 7,060 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:INHAL:EXPOS TO >1000 PPM MAY CAUSE HDCH, DROW & LASSITUDE, LOSS OF APPETITE, INABILITY TO CONC & IRRIT OF THROAT. IN ONE STUDY, PREGNANT RATS EXPOS TO 20,000 PPM SHOWED SEV NARCOS; OFFSPRING OF RATS DID NOT SHOW CLEAR EVID OF INCR INCIDENCE OF ABNORM. INGEST:EFFECTS DEPEND ON AMOUNT & RATE OF (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ:CONSUMPTION. SHORT TERM OVEREXP CAN CAUSE DRUNKENNESS, DEPRESS OF CNS, NAUS, VOMIT, DIARR, LIVER DMG, & DEATH. LONG TERM EXPOS CAN ALSO CAUSE LOSS OF APPETITE, WT LOSS, NERVOUSNESS, MEMORY LO SS, & MENTAL RETARDATION. IARC HAS RPTDRELATIONSHIP BETWEEN DRINKING ALCOHOLIC BEVERAGES & CANCER OF ORAL (ING 2) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:IF VICTIM IS CONSCIOUS & ABLE TO SWALLOW, HAVE VICTIM DRINK WATER TO DILUTE. NEVER GIVE ANYTHING BY MOUTH IF UNCON/HAVING CONVL. INDUCE VOMIT ONLY IF ADVISED BY PHYS/POIS CTL CTR. CALL PHYS/POI S CTL CTR IMMED. SKIN:IMMED FLUSH AFFECTED AREA W/PLENTY OF WATER WHILE REMOVING CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE REUSE. EYE:IMMED FLUSH W/PLENTY OF COOL WATER FOR @ LST 15 MINS. DO (ING 5) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:55.0F,12.8C Lower Limits:3.3% Upper Limits:19% Extinguishing Media:USE DRY CHEMICAL, "ALCOHOL RESISTANT" FOAM, OR CARBON DIOXIDE. Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER MAY BE INEFTIVE, BUT WATER APPLIED AS SPRAY CAN ABSORB SOME OF FIRE'S HEAT & SHOULD BE USED TO KEEP (SUPDAT) Unusual Fire/Explosion Hazard:ETHANOL VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION & FLASH BACK. ================== Accidental Release Measures ================== Spill Release Procedures:TURN OFF/REMOVE ALL IGNIT SOURCES. CONTAIN SPILLED MATL. TRANSFER TO SECURE CNTNRS. WHERE NEC, COLLECT USING ABSORB MEDIA. IN EVENT OF UNCONTROLLED RELEASE OF MATL, USER SHOULD DETERM IF RELEASE IS RE PORTABLE UNDER APPLIC LAWS & REGS. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT CNTNR AGAINST PHYSICAL DMG. DETACHED/OUTSIDE STOR IS PREF. INSIDE STORAGE SHOULD BE IN NFPA APPRVD FLAM LIQS STOR ROOM/CABINET. Other Precautions:ALL IGNIT SOURCES SHOULD BE ELIMINATED. SMKNG SHOULD BE PROHIBITED IN STOR AREAS. ELEC INSTALLATIONS SHOULD BE I/A/W ARTICLE 501 OF NTL ELEC CODE. NFPA 30, FLAM & COMBUST LIQS CODE, SHOULD BE FOLLOWED FOR ALL STOR & HNDLG. FREQUENT (ING 7) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE ENGINEERING CTLS ARE NOT FEASIBLE/SUFFICIENT TO ACHIEVE FULL CONFORMANCE W/ACCEPTABLE CRITERIA, USE NIOSH APPRVD RESP PROT EQUIP. RESPS SHOULD BE SELECTED BASED ON FORM & CONC OF CONTAM IN AIR & I/A/W OSHA (29 CFR 1910.134). Ventilation:ENGINEERING CTLS SHOULD BE USED WHENEVER FEASIBLE TO MAINTAIN CONCS BELOW ACCEPTABLE EXPOS CRITERIA, INCL BUT (ING 15) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . IMPERVIOUS CLTHG. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health MFR TRADE NAME/PART NO:ALCOHOL, USP, ETHYL ALCOHOL. FIRE FIGHT PROC:FIRE-EXPOS CNTNRS COOL. IF LEAK/SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE VAPS & TO PROTECT PERS ATTEMPTING TO STOP LEAK. W ATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOS & TO DILUTE SPILLS TO NONFLAMMABLE MIXTURE. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:173F,78C Melt/Freeze Pt:M.P/F.P Text:-173F,-114C Vapor Pres:44.6 @ 68F Vapor Density:1.59 Spec Gravity:0.7937 Evaporation Rate & Reference:NOT KNOWN Solubility in Water:COMPLETE Appearance and Odor:CLEAR LIQUID WITH ALCOHOL ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT W/ACETYL CHLORIDE OR OTHER OXIDIZING AGENTS MAY RESULT IN A VIOLENT REACTION. Stability Condition to Avoid:CONTACT W/ACETYL CHLORIDE OR OTHER OXIDIZING AGENTS MAY RESULT IN A VIOLENT REACTION. Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE CAN FORM UPON COMBUSTION. ==================== Disposal Considerations ==================== Waste Disposal Methods:ALL RECOVERED MATL SHOULD BE PACKAGED, LBLD, TRANSPORTED & DISPOSED OF/RECLAIMED IN CONFORMANCE W/APPLIC FEDERAL, STATE & LOCAL LAWS & REGS & IN CONFORMANCE W/GOOD ENGINEERING PRACTICES. RECLAIM WHERE POSSIBLE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.