RESIN TECHNOLOGY CO -- X-40 FOAM PART A, RT-5080-A  -- 8030-00N027857
<pre>=====================  Product Identification  =====================

Product ID:X-40 FOAM PART A, RT-5080-A
MSDS Date:08/01/1989
FSC:8030
NIIN:00N027857
Kit Part:Y
=== Responsible Party ===
Company Name:RESIN TECHNOLOGY CO
Address:2270 CASTLE HARBOR PLACE
City:ONTARIO
State:CA
ZIP:91761
Country:US
Info Phone Num:714-947-7224
Emergency Phone Num:714-947-7224
CAGE:RTECH
=== Contractor Identification ===
Company Name:RESIN TECHNOLOGY CO
Address:2270 CASTLE HARBOR PLACE
City:ONTARIO
State:CA
ZIP:91761
Country:US
Phone:714-947-7224
CAGE:RTECH

=============  Composition/Information on Ingredients  =============

Ingred Name:ING 16: SCBA. AIR PURIFYING (CARTRIDGE TYPE) RESPIRATORS
    ARE NOT APPROVED FOR PROTECTION AGAINST ISOCYANATES.
RTECS #:9999999ZZ

Ingred Name:VENT: MAY NEED TO BE CLEANED BY SCRUBBERS/FILTERS TO REDUCE
    ENVIRONMENTAL CONTAMINATION.
RTECS #:9999999ZZ

Ingred Name:OTHER EQUIP: HAVE EXCELLENT RESISTANCE. OTHER MATLS SUCH AS
    LATEX, PVC, POLYETHYLENE ARE LESS IMPERVIOUS. REFER (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: TO "GUIDELINES FOR SELECTION OF CHEMICAL PROTECTIVE
    CLOTHING" BY ACGIH. HAVE EYEWASH STATION & SAFETY (ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: SHOWER IN WORK AREA.
RTECS #:9999999ZZ

Ingred Name:RESP PROT: AIR RESPIRATOR W/FULL FCPIECE/AIR-SUPPLIED HOOD.
    FOR EMERG, USE NIOSH/MSHA APPRVD POSITIVE PRESS (ING 17)
RTECS #:9999999ZZ

Ingred Name:POLYMETHYLENE POLYPHENYL ISOCYANATE; (SIMILAR STRUCTURE
    OLIGOMERS)
CAS:9016-87-9
RTECS #:TR0350000
Fraction by Wt: 50%

Ingred Name:SUPP DATA: CHEST W/DFCLTY BRTHG. SYMPS MAY BE IMMED/DELAYED
    UP TO SEVERAL HOURS AFTER EXPOS. THERE ARE RPTS THAT (ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3: CHRONIC EXPOSURES MAY RESULT IN PERM DECREASES IN
    LUNG FUNCTION.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: REMOVE VICTIM TO FRESH AIR. IF NOT BRTHG,
    GIVE ARTF RESP, PREF MOUTH-TO-MOUTH. IF BRTHG IS (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5: LABORED, GIVE OXYGEN. CONSULT MEDICAL PERSONNEL.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: WATER(5-10% SODIUM CARBONATE MAY BE SUBSTITUTED
    FOR AMMONIUM HYDROXIDE). TREAT SPILL AREA W/DECOMTAM (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: SOLN, USING 10 PARTS SOLN TO EACH PART SPILL & ALLOW
    TO REACT FOR AT LEAST 10 MINS. CO*2 WILL BE EVOLVED (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: LEAVING INSOLUBLE POLYUREAS. FOR MAJOR SPILLS, CALL
    CHENTREC 800-424-9300.
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH: CNTNR DISP: DRUMS MUST BE DECONTAMD IN
    PROPERLY VENT AREAS BY PERS PROT FROM INHAL OF (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: ISOCYANATE VAPS. SPRAY/POUR 5-15 LITERS OF DECONTAM
    SOLN INTO DRUM, MAKING SURE WALLS ARE WELL RINSED. (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: LEAVE DRUM SOAKING UNSEALED FOR 48 HRS. POUR OUT
    DECONTAM SOLN & TRIPLE RINSE EMPTY CNTNR. PUNCTURE/(ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: OTHERWISE DESTROY RINSED CONTAINER BEFORE DISPOSAL.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: ISOCYANATES. THESE INDIVIDUALS SHOULD BE
    IDENTIFIED THROUGH BASELINE & ANNUAL EVAL & REMOVED FROM (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14: FURTHER EXPOS. MED EXAM SHLD INCLUDE MED HISTORY,
    VITAL CAPACITY & FORCED EXPIRATORY VOLUME AT 1 SECOND.
RTECS #:9999999ZZ

Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER; (MDI)
    (4,4'-DIPHENYLMETHANE-DIISOCYANATE	(SARA III).
CAS:101-68-8
RTECS #:NQ9350000
Fraction by Wt: 50%
OSHA PEL:0.02 PPM, C
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL,RAT) >10,000 MG/KG
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:INGEST: SINGLE DOSE OF PROD IS
    PRACTICALLY NONTOXIC BY INGEST. IRRIT OF MOUTH, PHARYNX, ESOPHAGUS
    & STOMACH CAN DEVELOP FOLLOWING INGEST. EYE: MATL WILL PROBABLY
    IRRIT HUMAN EYES FOLLOWING CONTACT. SK IN: NO IRRIT IS LIKELY
    FOLLOWING SHORT CONTACT PERIODS W/HUMAN SKIN. SKIN SENSIT & IRRIT
    MAY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: DEVEL AFTER RPTD/PRLNG CONT W/HUMAN
    SKIN. PRLNG/RPTD SKIN CONT W/MDI CAN INDUCE DELAYED SKIN RXNS SEV
    HOURS AFTER EXPOS. INHAL: VAPS/AEROSOLS CAN IRRIT EYES,NOSE & RESP
    PASSAGES. SEVERE OVER EXP MAY LEAD TO PULM EDEMA. MDI CAN INDUCE
    RESP SENSIT W/ASTHMA-LIKE SYMPS SIMILAR TO THOSE INDUCED BY (SUPP
    DATA)
Medical Cond Aggravated by Exposure:PREVIOUSLY SENSITIZED INDIVIDUALS
    OR TO INDIVIDUALS WITH EXISTING RESPIRATORY DISEASE, SUCH AS
    CHRONIC BRONCHITIS, EMPHYSEMA, ASTHMA. SENSITIZED INDIVIDUALS SHLD
    BE REMOVED FROM ANY FURTHER EXPOSURE.

=======================  First Aid Measures  =======================

First Aid:SKIN: WASH MATL OFF OF SKIN W/PLENTY OF SOAP & WATER. IF
    REDNESS, ITCHING, OR BURNING SENSIT DEVELS, GET MED ATTN. EYES:
    IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. IF REDNESS,
    ITCHING, BURNIN G SENSATION DEVEL, HAVE EYES EXAMINED &TREATED BY
    MED PERS. INGEST: GIVE 1-2 GLASSES OF WATER TO DRINK. IF GI SYMPS
    DEVEL, CONSULT MD. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS.
    INHAL: (ING 5)

=====================  Fire Fighting Measures  =====================

Flash Point Method:COC
Flash Point:425F,218C
Extinguishing Media:DRY CHEM, FOAM, CO*2, HALOGENATED AGENTS. IF H*2O
    IS USED,USE VERY LGE QTYS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
    PROTECTIVE EQUIPMENT . THE REACTION BETWEEN WATER & HOT ISOCYANATE
    MAY BE VIGOROUS.
Unusual Fire/Explosion Hazard:WATER CONTAMINATION WILL PRODUCE CO*2. DO
    NOT RESEAL CONTAMINATED CONTAINERS AS PRESSURE BUILDUP MAY RUPTURE
    THEM.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR SKIN, EYE, & RESP PROT DURING CLEANUP.
    SOAK UP MATL W/ABSORB & SHOVEL INTO A CHEM WASTE CNTNR. COVER
    CNTNR, BUT DO NOT SEAL & REMOVE FROM WORK AREA. PREPARE A DECONTAM
    SOLUTION OF 0.2-5% LIQ DETE RGENT & 3-8% CONC AMMONIUM HYDROXIDE
    IN(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN TIGHTLY SEALED CNTNRS TO PROT
    FROM ATMOS MOISTURE. STORE IN COOL AREA. PVNT SKIN/EYE CONTACT.
    AVOID BRTHG VAPS/AEROSOLS. OBSERVE TLV LMTS.
Other Precautions:WORKERS SHLD SHOWER & CHANGE TO FRESH CLTHG AFTER
    EACH SHIFT. SENSITIZED INDIVID SHLD NOT BE EXPOS TO PROD WHICH
    CAUSED SENSIT. INDIVIDUALS W/EXISTING RESP DISEASE SUCH AS CHRONIC
    BRONCHITIS, EMPHYSEM A/ASTHMA SHLD NOT BE EXPOS TO (ING 14)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:BECAUSE OF LOW VAP PRESS, VENT IS USUALLY
    SUFFICIENT TO KEEP VAPS <TLV AT ROOM TEMPS. EXCEPTIONS ARE WHEN
    MATLS ARE SPRAYED/HEATED. IF AIRBORNE CONCS EXCEED/ARE EXPECTED TO
    EXCEED TLV, USE NIOSH/MSHA	APPRVD POSITIVE PRESS SUPPLIED (ING 16)
Ventilation:USE LOC EXHST VENT TO KEEP AIRBORNE CONC <TLV. FOLLOW
    GUIDELINES IN ACGIH PUB "INDUSTRIAL VENT". EXHST AIR (ING 18)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEM WORK GOGS & FULL LNGTH FCSHLD
Other Protective Equipment:APRON-ARM COVERS-FULL BODY SUIT CONSTRUCTED
    OF BUTYL/NITRILE RUBBER/SARANEX COATED TYVEK/SOME NEOPRENE GARMENTS
    (ING 19)
Work Hygienic Practices:WASH CONTAMD CLOTHING BEFORE REWEARING.
Supplemental Safety and Health
BOIL PT:646F,341C(DECOMP). MATL TO AVOID:W/H*2O IS VERY SLOW <50C, BUT
    ACCELS AT >TEMPS & IN PRESENCE OF ALKALIES/TERTIARY AMINES/METAL
    CMPDS. SOME RXNS CAN BE VIOLENT. CNDTNS TO AVOID(POLY): OF CO*2 
    GAS MAY RUPTURE CLSD CNTNRS. EFTS OF OVEREXP: TDI (TOLUENE
    DIISOCYANATE). SYMPS INCL CHRONIC COUGH, TIGHTNESS OF (ING 3)

==================  Physical/Chemical Properties  ==================

HCC:N1
Boiling Pt:B.P. Text:646F,341C
Vapor Pres:<.0001@20C
Vapor Density:8.6
Spec Gravity:1.2
Solubility in Water:REACTS
Appearance and Odor:DARK BROWN, VISCOUS LIQUID WITH SLIGHT ODOR.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
WILL REACT W/ANY MTLS CNTNG ACTIVE HYDROGENS, E.G., H*2O, ALCOHOL,
    AMMONIA, AMINES, ALKALIES & ACIDS. THE RXN(SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUST PRODS: CO*2, CO, NITROGEN
    OXIDES, AMMONIA. TRACE AMOUNTS OF HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:HIGH TEMPS IN PRESENCE OF ALKALIES,
    TERTIARY AMINES, & METAL CMPDS WILL ACCELERATE POLYMERIZATION. POSS
    EVOL (SUPP DATA)

====================  Disposal Considerations  ====================

Waste Disposal Methods:SLOWLY STIR ISOCYANATE WASTE INTO DECOMTAM SOLN
    USING 10 PARTS SOLN FOR EACH PART ISOCYANATE. LET STAND FOR 48 HRS,
    ALLOWING EVOLVED CO*2 TO VENT AWAY. NEUT WASTE. NEITHER SOLID NOR
    LIQ PORTION IS HAZ	WASTE UNDER RCRA, 40 CFR 261. (ING 10)

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