EASTMAN KODAK COMPANY -- 146 4486, CONC, KODAK RAPID SELENIUM TONER -- 6750-01-428-0375
===================== Product Identification ===================== Product ID:146 4486, CONC, KODAK RAPID SELENIUM TONER MSDS Date:09/14/2000 FSC:6750 NIIN:01-428-0375 Status Code:A === Responsible Party === Company Name:EASTMAN KODAK COMPANY Address:343 STATE STREET City:ROCHESTER State:NY ZIP:14650 Country:US Info Phone Num:716-477-3194 MSDS :800- 242-2424 Emergency Phone Num:716-722-5151 Preparer's Name:NOT PROVIDED CAGE:19139 === Contractor Identification === Company Name:EASTMAN KODAK CO GOVERNMENT MARKETS CONTRACTS Address:343 STATE ST Box:City:ROCHESTER State:NY ZIP:14650-1115 Country:US Phone:716-722-5151/(800) 242-2424 CAGE:19139 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:55. Maxumum % Wt:60. Other REC Limits:NOT PROVIDED Code:F Code:F Ingred Name:AMMONIUM THIOSULFATE CAS:7783-18-8 RTECS #:XN6465000 = Wt:27. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:SODIUM SULFITE CAS:7757-83-7 RTECS #:WE2150000 Minumum % Wt:10. Maxumum % Wt:15. Other REC Limits:NOT PROVIDED OSHA PEL:NOT PROVIDED ACGIH TLV:NOT PROVIDED Ingred Name:SODIUM SELENITE CAS:10102-18-8 RTECS #:VS7350000 = Wt:2. Other REC Limits:NOT PROVIDED OSHA PEL:0.2 MG/M3 ACGIH TLV:0.2 MG/M3 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) 500-5,000 MG/KG Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW HAZARD FOR RECOMMENDED HANDLING. IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATO RY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT IRRITATION. SKIN: HARMFUL IF ABSORBED THROUGH SKIN. THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BEEN REPORTED. INGESTION: MAY BE HARMFUL IF SWALLOWED. Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION (COMPONENTS PRESENT AT 0.1% OR MORE): - INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC): NONE - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH): NON E - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE Effects of Overexposure:INHALATION: IN CONTACT WITH STRONG ACIDS OR IF HEATED, SULFITES MAY LIBERATE SULFUR DIOXIDE GAS. SULFUR DIOXIDE GAS IS IRRITATING TO THE RESPIRATORY TRACT. SOME ASTHMATICS OR HYPERSENSITIVE INDIVIDUAL S MAY EXPERIENCE DIFFICULT BREATHING. EYES: MAY CAUSE TRANSIENT IRRITATION. SKIN: THIS MATERIAL HAS A LOW POTENTIAL TO CAUSE ALLERGIC SKIN REACTIONS; HOWEVER, CASES OF HUMAN SKIN SENSITIZATION HAVE BE EN REPORTED. Medical Cond Aggravated by Exposure:SOME ASTHMATICS, HYPERSENSITIVE OR SULFITE-SENSITIVE INDIVIDUALS MAY EXPERIENCE DIFFICULT BREATHING, WHEEZING, CHEST TIGHTNESS, STOMACH UPSET, HIVES, FAINTNESS, WEAKNESS AND DIARRHEA. ======================= First Aid Measures ======================= First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: ANY MATERIAL THAT CONTACTS EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET M EDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. WASH CONTAMINAT ED CLOTHING BEFORE REUSE. DESTROY OR THOROUGHLY CLEAN CONTAMINATED SHOES. INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. CALL PHYSICI AN OR POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:FLOOD WITH WATER. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS. Unusual Fire/Explosion Hazard:SOLUTION CONTAINS A STRONG REDUCING AGENT. DRIED PRODUCT RESIDUE CAN ACT AS A REDUCING AGENT. ================== Accidental Release Measures ================== Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL, THEN PLACE IN CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. COLLECT IN NONCOMBUSTIBLE CONTAINER FOR PR OMPT DISPOSAL. Neutralizing Agent:NOT PROVIDED ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED TO PREVENT THE LOSS OF WATER. KEEP AWAY FROM INCOMPATIBLE SUBSTANCES. DO NOT STORE OR SHIP TOGETHER WITH COMBUSTIBLE MATERIAL. STORE IN ORIGINAL CONTAINER. AVOID BREATHIN G MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. WASH THOROUGHLY AFTER HANDLING. Other Precautions:USE WITH ADEQUATE VENTILATION. KEEP AWAY FROM COMBUSTIBLE MATERIAL. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY. KEEP FROM CONTACT WITH OXIDIZING MATERIALS, HIGHLY OXYGENATED OR HALOGENATED SOLVEN TS, ORGANIC COMPOUNDS CONTAINING REDUCIBLE FUNCTIONAL GROUPS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED. A RESPIRATOR SHOULD BE WORN IF HAZARDOUS DECOMPOSITION PRODUCTS ARE LIKELY TO BE OR HAVE BEEN RELEASED. RESPIRATOR TYPE: FULL-FACE POSITIVE-PRESSURE AIR-SUPPLIED. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. Protective Gloves:WEAR IMPERVIOUS GLOVES AND PROTECTIVE CLOTHING APPROPRIATE FOR RISK OF EXPOSURE Eye Protection:WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES). Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER Work Hygienic Practices:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE Supplemental Safety and Health USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABL E. N/K = UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT DETERMINED. N/E = NOT ESTABLISHED. ================== Physical/Chemical Properties ================== HCC:B3 NRC/State Lic Num:NOT RELEVANT Boiling Pt:>100.C, 212.F Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED Decomp Temp:Decomp Text:NOT PROVIDED Vapor Pres:(68F):24 MBAR (18 MM HG) Vapor Density:0.6 Spec Gravity:1.32 pH:9.0 Viscosity:NOT PROVIDED Evaporation Rate & Reference:NOT PROVIDED Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID - CHARACTERISTIC MILD ODOR. Percent Volatiles by Volume:55- 60 WT Corrosion Rate:NOT PROVIDED ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES BASES, SODIUM HYPOCHLORITE (BLEACH), STRONG OXIDIZING AGENTS, STRONG ACIDS, COMBUSTIBLE MATERIAL, HALOGENATED MATERIALS. CONTACT WITH BASE LIBERATES FLAMMABLE MATERIAL. Stability Condition to Avoid:NOT PROVIDED Hazardous Decomposition Products:SULFUR DIOXIDE, AMMONIA, CHLORAMINE, OXIDES OF SULFUR, OXIDES OF NITROGEN. =================== Toxicological Information =================== Toxicological Information:EFFECTS OF EXPOSURE: GENERAL: CONTAINS SODIUM SELENITE. OVEREXPOSURE TO SELENIUM COMPOUNDS MAY CAUSE LIVER AND KIDNEY DAMAGE, NEUROLOGICAL EFFECTS, FATIGUE, IRRITABILITY, HAIR LOSS, SKIN LESIONS , NAUSEA AND VOMITING, GARLIC ODOR OF BREATH AND SWEAT, AND METALLIC TASTE. ACUTE TOXICITY DATA: ORAL LD-50 (RAT): 0.5-5.0 G/KG SKIN IRRITATION: SLIGHT EYE IRRITATION: SLIGHT DERMAL L D-50: > 10 ML/KG ===================== Ecological Information ===================== Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS OF THE PREPARATIONS. POTENTIAL TOXICITY: FISH LC50 MG/L: >100. DAPHNID EC50 MG/L: >100. ALGAL IC50 MG/L: >100. ORGANICS READILY DEGRAD ABLE (>70%): NOT APPLICABLE. POTENTIAL BIOACCUMULATION: LOG POW <1. COD (APPROXIMATE G/L): 178. BOD5 (APPROXIMATE G/L): 150. POTENTIAL TOXICITY: WASTE TREATMENT MICROORGANISMS EC50 (MG/L): >100. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL IS SUBJECT TO NATIONAL, STATE, OR LOCAL LAWS. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNING S EVEN AFTER CONTAINER IS EMPTIED. =================== MSDS Transport Information =================== Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE: (716) 722-2400 BETWEEN 8 A.M. AND 5 P.M. (EASTERN STANDARD TIME), MONDAY THROUGH FRIDAY . ===================== Regulatory Information ===================== SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART 372: SELENIUM COMPOUNDS (SODIUM S ELENITE); AMMONIUM THIOSULFATE, (AS CHEMICAL SOURCE OF AQUEOUS AMMONIA). Federal Regulatory Information:NOT PROVIDED State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER: NONE - MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.