DOW AGROSERVICES -- SPIKE (*) 20P HERBACIDE -- 6840-01-356-8894
===================== Product Identification ===================== Product ID:SPIKE (*) 20P HERBACIDE MSDS Date:08/25/2000 FSC:6840 NIIN:01-356-8894 Status Code:A === Responsible Party === Company Name:DOW AGROSERVICES Address:9330 ZIONSVILLE ROAD Box:681428 City:INDIANAPOLIS State:IN ZIP:46268-1189 Country:US Info Phone Num:800-992-5994 Emergency Phone Num:800-992-5994 Resp. Party Other MSDS Num.:004006 CAGE:EO369 === Contractor Identification === Company Name:DOW AGROSERVICES Address:9330 ZIONSVILLE ROAD Box:681428 City:INDIANAPOLIS State:IN ZIP:46268-1189 Country:US Phone:800-992-5994 CAGE:EO369 ============= Composition/Information on Ingredients ============= Ingred Name:TEBUTHIURON: N-(5-(1,1-DI-METHYLETHYL)-1,3,4-THIADIAZOL-2-YL)-N,N'-DIMETHYLUREA CAS:34014-18-1 RTECS #:YS4250000 = Wt:20. Other REC Limits:NONE RECOMMENDED Ingred Name:INERT INGREDIENTS, TOTAL INCLUDING: CLAY (KAOLIN, CRYSTALLINE SILICA) CAS:1332-58-7 RTECS #:GF1670500 = Wt:80. ===================== Hazards Identification ===================== Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYE-MAY CAUSE SLIGHT EYE IRRITATION WITH CORNEAL INJURY. SKIN-ESSENTIALLY NON-IRRITATING TO SKIN. A SINGLE PROLONGED EXPOSURE IS NOT LIKELY TO RESULT IN THE MATERIAL BEING ABSORBED THROUGH SKIN IN HAR MFUL AMOUNTS. INGESTION-SINGLE DOSE ORAL TOXICITY IS LOW. SMALL AMOUNTS SWALLOWED INCIDENTAL TO NORMAL HANDLING ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, LARGE AMOUNTS MAY CAUSE INJURY. INHALATION-AT R OOM TEMPERATURE, VAPORS ARE MINIMAL DUE TO PHYSICAL PROPERTIES; A SINGLE EXPOSURE IS NOT LIKELY TO BE HAZARDOUS. SYSTEMIC EFFECTS-IN ANIMALS, HAS BEEN SHOWN TO CAUSE RBC, KIDNEY & PANCREATIC EFFECTS. Explanation of Carcinogenicity:TEBUTHIURON DID NOT CAUSE CANCER IN LABORATORY ANIMALS. CRYSTALLINE SILICA IS LISTED AS A CARCINOGEN FOR HAZARD COMMUNICATION PURPOSES UNDER OSHA STANDARD 29CFR 1910.1200. THE CLAY COMPONENT MAY CONTA IN CRYSTALLINE SILICA, WHICH HAS CAUSED CANCER IN LAB ANIMALS. ======================= First Aid Measures ======================= First Aid:EYES-IRRIGATE WITH FLOWING WATER. IMMEDIATELY AND CONTINUOSLY FOR 15 MINUTES. CONSULT MEDICAL PERSONNEL. SKIN-WASH OFF IN FLOWING WATER OR SHOWER. INGESTION-IF SWALLOWED, SEEK IMMEDIATE MEDICAL ATTENT ION. DO NOT INDUCE VOMITING UNLESS DIRECTED BY MEDICAL PERSONNEL. INHALATION-REMOVE TO FRERSH AIR IF SYMPTOMS OCCUR. CONSULT A PHYSICIAN. NOTE TO PHYSICIAN-NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREAT MENT BASED ON JUDGEMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT. ===================== Fire Fighting Measures ===================== Autoignition Temp:=750.C, 1382.F Extinguishing Media:USE WATER FOG, FOAM OR CARBON DIOXIDE IF PRODUCT IS INVOLVED IN FIRE. Fire Fighting Procedures:WEAR POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING IF PRODUCT IS INVOLVED IN FIRE. Unusual Fire/Explosion Hazard:WILL EMIT TOXIC VAPORS AS IT BURNS. ================== Accidental Release Measures ================== Spill Release Procedures:CONTAIN AND SWEEP UP MATERIAL FROM SMALL SPILLS AND DISPOSE OF WASTE. REPORT LARGE SPILLS TO DOW AGROSCIENCES ON 800-992-5994. PREVENT RUN-OFF. ====================== Handling and Storage ====================== Handling and Storage Precautions:HANDLING-KEEP OUT OF REACH OF CHILDREN. CAUSES EYE IRRITATION. KEEP OUT OF REACH OF CHILDREN. CAUSES EYE IRRITATION. HARMFUL IF SWALLOWED, INHALD OR ABSORBED THROUGH THE SKIN. AVOID BREATHING DUST & C ONTACT WITH SKIN, EYES OR CLOTHING. Other Precautions:STORAGE-STORE IN THE ORGINAL CONTAINER IN A DRY AREA. DISPOSAL:CONTACT YOUR STATE PESTICIDE OR ENVIRONMENTAL CONTROL AGENCY, OR THE HAZARDOUYS WASTE REPRESENTATIVE AT THE NEAREST EPA REGIONAL OFFICE F OR GUIDANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ATMOSPHERIC LEVELS SHOULB BE MAINTAINED BELOW THE EXPOSURE GUIDELINE. Ventilation:PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES. Eye Protection:USE CHEMICAL GOGGLES. Other Protective Equipment:NO PRECAUTIONS OTHER THAN CLEAN BODY-COVERING CLOTHING SHOULD BE NEEDED. Work Hygienic Practices:WASH THOROUGHLY WITH SOAP & WATER AFTER HANDLING. REMOVE CONTAMINATED CLOTHING & WASH BEFORE RESUE. Supplemental Safety and Health APPLICATORS & ALL OTHER HANDLERS: REFER TO THE PRODUCT LABEL FOR PERSONAL PROTECTIVE CLOTHING & EQUIPMENT. ================== Physical/Chemical Properties ================== HCC:T5 pH:>4.3 Solubility in Water:NEGLIGIBLE Appearance and Odor:GREY TO DARK BROWN PELLET; FAINT MUSTY ODOR. ================= Stability and Reactivity Data ================= NONE KNOWN. Stability Condition to Avoid:THE HERBICIDAL PROPERTIES OF THIS PRODUCT REQUIRE CAUTION IN HANDLING, STORAGE AND TRANSPORTATION-VERY POTENT HERBICIDE. Hazardous Decomposition Products:OXIDES OF NITROGEN AND SULFUR MAY BE FORMED IF PRODUCT IS INVOLVED IN FIRE. Conditions to Avoid Polymerization:DOES NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:TERATOLOGY (BIRTH EFFECTS): FOR TEBUTHIURON, BIRTH DEFECTS ARE UNLIKELY. EVEN EXPOSURES HAVING AN ADVERSE EFFECTS ON THE THE MOTHER SHOULD HAVE NO EFFECTS ON THE FETUS. REPRODUCTIVE EFFECTS: TEBUTHIU RON, DID NOT INTEFERE WITH REPRODUCTION IN ANIMAL STUDIES. MUTAGENICITY: IN-VITRO MUTAGENICITY STUDIES WERE NEGATIVE IN SOME CASES & POSITIVE IN OTHER CASES. ANIMAL MUTAGENICITY STUDIES WERE NEGATIVE. THE LD50 FOR SKIN ABSORPTION IN RABBITS IS>000 MG/KG. THE ORAL LD50 FOR RATS IS>2000 MG/KG. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL DATA: DO NOT APPLY THIS HERBICIDE NEAR DESIRABLE TREES OR OTHER WOODY SPECIES. EXPOSURE OF EVEN A SMALL PART OF A PLANT ROOT SYSTEM TO THIS PRODUCT MAY CAUSE SEVERE PLANT INJURY OR DEATH . DO NOT APPLY DIRECTLY TO WATER, TO AREAS WHERE SURFACE WATER IS PRESENT, OR TO INTERTIDAL AREAS BELOW THE MEAN HIGH WATER MARK. DO NOT CONTAMINATE WATER BY CLEANING EQUIPMENT, DISPOSING OF EQUIPMENT WASHWATERS, OR DISPOSING OF WASTES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT CONTAMINATE FOOD, FEED, OR WATER BY STORAGE OR DISPOSAL. WASTES ARE TOXIC. IMPROPER DISPOSAL OR EXCESS WASTE, SPRAY MIXTURE, OR RINSATE IS A VIOLATION OF FEDERAL LAW. IF WASTES RESULTING FROM T HE USE OF THIS PRODUCT CANNOT BE DISPOSED OF ACCORDING TO LABEL INSTRUCTIONS, DISPOSE OF THESE WASTE S AT AN APPROVED FACILITY. "SEE OTHER PRECAUTIONS" =================== MSDS Transport Information =================== Transport Information:FOR DOT REGULATORY INFORMATION, IF REQUIRED, CONSULT TRANSPORTATION REGULATIONS, PRODUCT-SHIPPING PAPERS, OR CONSULT YOUR DOW AGROSCIENCE REPRESENTATIVE. ===================== Regulatory Information ===================== SARA Title III Information:SARA 313: TEBUTHIURON, 034014-18-1, 20%. SARA HAZARD CATEGORY: AN IMMEDIATE HEALTH HAZARD. A DELAYED HEALTH HAZARD. Federal Regulatory Information:TSCA: ALL INGREDIENTS ARE ON THE TSCA INVENTORY OR ARE NOT REQUIRED TO BE LISTED ON THE TSCA INVENTORY. OSHA HAZARD COMMUNICATION STANDARD: THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSH A HAZARD COMMUNICATION STANDRAD, 29 CFR 1910.1200. CERCLA: TO THE BEST OF OUR KNOWLEDGE, THIS PRODUCT CONTAINS NO CHEMICAL SUBJECT TO REPORTING UNDER CERCLA. State Regulatory Information:KAOLIN, 001332-58-7, PA1=PENNSYLVANIA HAZARDOUS SUBSTANCE (PRESENT AT >OR=TO 1.0%). ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.