SYSCO CHEMICAL -- RELIANCE DISINFECTANT BLEACH, 4000147 -- 6850-00N091506
===================== Product Identification ===================== Product ID:RELIANCE DISINFECTANT BLEACH, 4000147 MSDS Date:07/01/1994 FSC:6850 NIIN:00N091506 Status Code:A === Responsible Party === Company Name:SYSCO CHEMICAL Address:1390 ENCLAVE PARKWAY City:HOUSTON State:TX ZIP:77077 Country:US Info Phone Num:713-584-1790 Emergency Phone Num:800-228-5635 Chemtrec Ind/Phone:(800)424-9300 CAGE:SYSCO === Contractor Identification === Company Name:SYSCO CHEMICAL Address:1390 ENCLAVE PARKWAY Box:City:HOUSTON State:TX ZIP:77077 Country:US Phone:713-584-1790 CAGE:SYSCO ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYPOCHLORITE (5-6% AVAILABLE CHLORINE) CAS:7681-52-9 RTECS #:NH3486300 Minumum % Wt:5.25 Maxumum % Wt:6.6 Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:CHLORINE CAS:7782-50-5 RTECS #:FO2100000 Minumum % Wt:5. Maxumum % Wt:6. Other REC Limits:N/K OSHA PEL:C3 MG/M3;C1 PPM OSHA STEL:N/K ACGIH TLV:1.5 MG/M3;0.5 PPM ACGIH STEL:2.9 MG/M3;1 PPM EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS Ingred Name:SODIUM HYDROXIDE CAS:1310-73-2 RTECS #:WB4900000 Minumum % Wt:.2 Maxumum % Wt:.5 Other REC Limits:N/K OSHA PEL:2 MG/M3 OSHA STEL:N/K ACGIH TLV:2 MG/M3 ACGIH STEL:C2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INGESTION: CAN CAUSE CORROSION OF MUCOUS MEMBRANES, SEVERE ESOPHAGEAL BURNS AND PERFORATION OF ESOPHAGUS OR STOMACH. INHALATION: INHALATION OF VAPORS CAN CAUSE BRONCHIAL IRRITATION, COUGHING, DIFFICUL TY IN BREATHING, NAUSEA AND PULMONARY EDEMA. EYES: CORROSIVE TO EYES; MAY CAUSE SEVERE AND PERMANENT DAMAGE. SKIN: SEVERE IRRITANT; CONTACT CAN PRODUCE BLISTERING AND ECZEMA. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:INGEST: DO NOT INDUCE VOMIT. IMMED DRINK LGE QTY OF WATER. DO NOT USE ACIDIC ANTIDOTES/SODIUM BICARBONATE (BAKING SODA). CALL MD/POIS CTL CTR IMMED. INHAL: IF EXPOSED TO EXCESS VAP LEVELS, REMOVE TO F RESH AIR & SEEK MED ATTN IF COUGH/OTHER SYMPS DEVELOP. EYES: IMMED FLUSH W/PLENTY OF COOL, RUNNING WATER. REMOVE CONT LENSES IF APPLIC, & CONTINUE FLUSHING FOR AT LEAST 15 MINS. GET MED ATTN IMMED. SK IN: FLUSH W/COPIOUS AMTS OF WATER & WASH W/SOAP & WATER. IF IRRIT DEVELOPS/PERSISTS, GET MED ATTN. REMOVE CLTHG & WASH BEFORE REUSE. (SUP DAT) ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:IF INVOLVED IN A FIRE, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL OR WATER FOG. USE EXTINGUISHING MEDIA THAT IS APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . AVOID FUMES FROM SPILLED OR EXPOSED LIQUID. COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY FROM A SAFE DISTANCE. Unusual Fire/Explosion Hazard:NOT FLAMMABLE OR COMBUSTIBLE. SODIUM HYPOCHLORITE BLEACH IS A STRONG OXIDIZING AGENTS AND DECOMPOSES WHEN HEATED. DECOMPOSITION PRODUCTS MAY CAUSE CONTAINERS TO EXPLODE. VIGOROUS REACTIONS MAY OCCUR W ITH ORGANIC MATERIALS OR OXIDIZABLE MATERIALS, CAUSING FIRES. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS: DILUTE PRODUCT BY FLOODING AREA WITH LARGE QUANTITY OF WATER AND FLUSH TO SANITARY SEWER. LARGE SPILLS: CONTAIN RUN-OFF BY DIKING WITH SUITABLE MATERIAL. SOAK UP LIQUID ON INERT ABSORBEN T AND TRANSFER TO APPROVED CONTAINER. PREVENT SPILL FROM ENTERING SEWERS OR WATERWAYS. ====================== Handling and Storage ====================== Handling and Storage Precautions:USE PERSONAL PROTECTIVE EQUIPMENT AND WEAR SUITABLE CHEMICAL-RESISTANT CLOTHING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. FOLLOW LABEL DIRECTIONS CLOSELY. STORE UPRIGHT IN A COOL (BELOW 85F), DR Y, WELL-VENTILATED AREA. KEEP AWAY FROM HEAT OR DIRECT SUNLIGHT. Other Precautions:SEPARATE FROM INCOMPATIBLE MATERIALS, SUCH AS ACIDS, AMMONIA, SOAP-BASED PRODUCTS, OR ORGANIC MATERIALS. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. KEEP AWAY FROM CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT NORMALLY NECESSARY; USE NIOSH APPROVED RESPIRATOR FOR CONCENTRATED VAPORS. Ventilation:USE LOCAL VENTILATION TO REMOVE VAPORS AT THE SOURCE. Protective Gloves:REQUIRED; USE IMPERVIOUS PVC OR NEOPRENE WITH LONG GAUNTLET. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES AND FULL LENGTH FACESHIELD . Other Protective Equipment:EYEWASH & DELUGE SHWR MTG ANSI DESIGN CRIT . BOOTS RECOMMENDED TO PROTECT SHOES & FEET WHEN USING PROD FOR FLOOR CLEANING. APRON RECOMMENDED TO AVOID SKIN CONT & PROTECT CLOTHING FROM DAMAGE. Work Hygienic Practices:AVOID BREATHING VAPORS. DO NOT STORE NEAR FOOD STUFFS, WATER OR FEED. PROTECT EYES, SKIN AND CLOTHING FROM CONTACT WITH THIS PRODUCT. WASH AFTER HANDLING AND BEFORE EATING. Supplemental Safety and Health FIRST AID PROC: NOTE TO MD: INFO PERTAINING TO INGEST TOXICITY, THERAPY, SYMPTOMATOLOGY & TREATMENT CAN BE FOUND IN CLINICAL TOXICOLOGY OF COMMERCIAL PRODS, AUTHORED BY GOSSELIN, SMITH & HODGE & PUBLI SHED BY WILLIAMS & WILKINS, BALTIMORE, MARYLAND. SEE LISTING FOR HYPOCHLORITE IN THERAPEUTIC INDEX, HLTH HAZ SECTION. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=-2.2C, 28.F Vapor Pres:17.5 MM HG @ 20C Spec Gravity:1.080 pH:12.0 - 12.8 Solubility in Water:COMPLETE Appearance and Odor:CLEAR PALE YELLOW LIQUID WITH CHLORINE ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ACIDS, AMMONIA, ETHER, UREA, OXIDIZABLE MATERIALS, SOAPS, OILS, GREASES, PHENOLIC DISINFECTANTS AND METALS (INCLUDING NICKEL, COPPER, TIN, ALUMINUM AND IRON). Stability Condition to Avoid:HEAT OR DIRECT SUNLIGHT; TEMPERATURES ABOVE 85F. DO NOT MIX WITH SOLUTIONS CONTAINING AMMONIA. Hazardous Decomposition Products:CHLORINE GAS, FROM CONTACT WITH HIGHLY ACIDIC MATERIALS. CHLORAMINES, FROM CONTACT WITH AMMONIA. POLYCHLORINATED PHENOLS, FROM CONTACT WITH PHENOLIC DISINFECTANTS. =================== Toxicological Information =================== Toxicological Information:THIS PRODUCT DOES NOT CONTAIN ANY KNOWN TO ANTICIPATED CARCINOGENS ACCORDING TO THE CRITERIA OF THE NTP ANNUAL REPORT ON CARCINOGENS AND OSHA 29 CFR 1910.Z. OTHER EFFECTS: ACUTE: TOXICITY ARISES FROM CORROSIVE ACTIVITY; STEMS FOR OXIDIZING POTENCY, A FUNCTION OF CONCENTRATION. CHRONIC: NOT DETERMINED. ===================== Ecological Information ===================== Ecological:CONSIDERED BIODEGRADABLE. BOD/COD VALUE: NOT ESTABLISHED. ECOTOXICITY: NO DATA AVAILABLE. ==================== Disposal Considerations ==================== Waste Disposal Methods:IF I/A/W NPDES PERMIT/APPRVD BY LOC SEWAGE TREATMENT PLANT AUTH, SML AMTS MAY BE FLUSHED TO SANITARY SEWER W/PLENTY OF WATER. LGE AMTS OF UNUSED PROD MUST BE DISPOSED OF AS HAZ WASTE AT APPRVD HAZ WAS TE MANAGEMENT FACILITY. DISPOSE OF I/A/W LOC, STATE, & FED REGS . (OTHER INFO) =================== MSDS Transport Information =================== Transport Information:DOT CLASSIFICATION: HAZARDOUS. DESCRIPTION: CONSUMER COMMODITY, ORM-D. EXEMPTED BY DOT FOR CONTAINERS OF 1 GALLON OR LESS. SYSCO HM CODE: NONE. ===================== Regulatory Information ===================== SARA Title III Information:SODIUM HYDROXIDE AND SODIUM HYPOCHLORITE (SECTION 304). Federal Regulatory Information:EPA REGISTERED (UNDER FIFRA): 1672-20004-29055; 9009-15-29055; 51790-20004-29055. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.