PBI/GORDON CORP -- 840, TRIMEC BROADLEAF HERBICIDE BENTGRASS F  -- 6840-00N031306
<pre>=====================  Product Identification  =====================

Product ID:840, TRIMEC BROADLEAF HERBICIDE BENTGRASS F
MSDS Date:01/14/1987
FSC:6840
NIIN:00N031306
=== Responsible Party ===
Company Name:PBI/GORDON CORP
Address:300 SOUTH 3RD ST
City:KANSAS CITY
State:MO
ZIP:66118-1110
Country:US
Info Phone Num:816-421-4070
Emergency Phone Num:816-421-4070;913-342-8783
CAGE:EO415
=== Contractor Identification ===
Company Name:PBI-GORDON CORPORATION
Address:1217 WEST 12TH STREET
City:KANSAS CITY
State:MO
ZIP:64101
Country:US
Phone:816-421-4070
CAGE:52228
Company Name:PBI/GORDON CORP
Address:1217 WEST 12TH ST
City:KANSAS CITY
State:MO
ZIP:64101
Country:US
Phone:816-421-4070/913-342-8783
CAGE:EO415

=============  Composition/Information on Ingredients  =============

Ingred Name:DIMETHYLAMINE (DMA) (SARA III)
CAS:124-40-3
RTECS #:IP8750000
Fraction by Wt: 4.91%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:SUPP DATA: FOR CHILDREN UNDER 12 YRS: ACTIVATED CHARCOAL
    30-50 GRAM IN SLURRY OF 6-8 OZ TAP WATER. TREATMENT IS (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5: ENTIRELY SYMPTOMATIC.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC:  WEAR HAND GLOVES & PROT CLTHG/SHOES,
    NIOSH/MSHA APRPOVED SCBA. DIKE FAR AHEAD OF SPILL FOR LATER (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: DISPOSAL. CNTN SPILL WITH
    DRI-RITE/SAND/NON-COMBUSTIBLE ABSORB. COLLECT INTO DOT DRUMS,
    COVER, MARK AND (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: REMOVE. WASH AREA WITH WATER.
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED

Ingred Name:WASTE DISP METH: FEDERAL LAW. IF THESE WASTES CANNOT BE
    DISPOSED OF BY USE ACCORD TO LABEL INSTRTUCTIONS, CNTCT (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10: YOUR STATE PESTICIDE OR ENVIRONMENTAL CONTROL
    AGENCY, OR THE HAZ WASTE REPRESENTATIVE AT THE NEAREST EPA(ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: REGIONAL OFFICE FOR GUIDANCE. CNTNR DISP: TRIPLE
    RINSE (OR EQUIVALENT). THEN OFFER FOR RECYCLING OR (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: RECNDTNG/PUNCTURE & DISPOSE OF IN A SANITARY
    LANDFILL/BY OTHER PROC APPRVD BY FED, STATE & LOCAL AUTHORITIES.
RTECS #:9999999ZZ

Ingred Name:ACETIC ACID, (2,4-DICHLOROPHENOXY)-; (2,4-D) (SARA III)
CAS:94-75-7
RTECS #:AG6825000
Fraction by Wt: 5.08%
ACGIH TLV:10 MG/M3 (MFR)
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:PROPIONIC ACID, 2-((4-CHLORO-O-TOLYL)OXY)-;
    (2-(2-METHYL-4-CHLOROPHENOXY) PROPIONIC ACID) (MECOPROP)
CAS:93-65-2
RTECS #:UE9750000
Fraction by Wt: 16.40%

Ingred Name:BENZOIC ACID, 3,6-DICHLORO-2-METHOXY-;
    (3,6-DICHLORO-O-ANISIC ACID) (DICAMBA)  (SARA III)
CAS:1918-00-9
RTECS #:DG7525000
Fraction by Wt: 2.10%
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50: (ORAL,RAT) > 1500 MG/KG
Routes of Entry: Inhalation:YES  Skin:NO  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:CONTACT MAY CAUSE SKIN IRRITATION.
    CONTACT MAY CAUSE EYE BURNS. CHRONIC: MODERATELY IRRIT TO SKIN,
    EYES, AND RESP GI LININGS. INGESTION OF LARGE AMOUNTS MAY RESULT IN
    SEVERE METABOLIC ACIDOSIS FOLLOWE D BY MYOTONIA, MYOGLOBINAURIA AND
    ELEVATED SERUM CREATING PHOSPHOKINASE.
Explanation of Carcinogenicity:NOT RELEVENT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYES:FLUSH CONTAM CHEM FROM EYES W/COPIOUS AMTS OF CLEAN H2O
    FOR @ LST 15 MIN. SKIN:BATHE & SHAMPOO W/SOAP & H2O TO REMOVE CHEM
    FROM SKIN & HAIR. INDIVIDUALS W/CHRONIC SKIN DISEASE/KNOWN SENSIT
    SHOULD  AVOID CNTCT. INHAL: IF SYMP OF ILLNESSOCCUR DURING/AFTER
    INHAL, REMOVE VICTIM FROM CNTCT W/MATL FOR @ LST 2 DAYS. INGEST:IF
    SUBSTANTIAL AMT OF PROD IS INGESTED, SPONTANEOUS EMESIS (SUPP DATA)

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER LARGE FIRES-WATER
    SPRAY/FOG/FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROT
    EQUIPMENT . FIGHT FIRE FROM MAXIMUM DISTANCE. ISOLATE HAZARD AREA
    AND DENY ENTRY. KEEP UNNEC PEOPLE AWAY.
Unusual Fire/Explosion Hazard:PROD WILL BOIL & MAY BURN DUE TO PRLNGD
    HEATING @ HIGH TEMP, BUT WILL NOT IGNITE. RUN OFF FROM FIRE CTRL
    AREA OR DILUTION H2O MAY CAUSE POLLLUTION. (SUPP DATA)

==================  Accidental Release Measures  ==================

Spill Release Procedures:SML SPILLS:DO NOT TOUCH SPILLED PROD. WEAR
    HAND GLOVES & PROT CLOTHING. CONTAIN SPILL
    W/DRI-RITE/SAND/NON-COMBUST ABSORB. COLLECT INTO DOT DRUMS, COVER,
    MARK & REMOVE. FLUSH AREA W/H2O, IF POSS. LRG S PILLS:DO NOT TOUCH
    SPILLED PROD. (ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN ORIGINAL CONTAINER IN A
    CLOSED STORAGE AREA INACCESSIBLE TO CHILDREN OR PETS. KEEP FROM
    FREEZING.
Other Precautions:TO PVNT CROSS-CONTAM, DO NOT STORE NEAR HERBICIDES,
    FERTILIZERS, INSECTICIDES, FUNGICIDES OR NEAR SEEDS. HARMFUL IF
    SWALLOWED. AVOID CONTACT WITH SKIN, EYES OR CLOTHING. AVOID
    BREATHING SPRAY MIST.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WHERE EXPOSURE LIMITS ARE EXCEEDED WEAR SUITABLE
    NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:GOOD VENTILATION OF WORK PLACE IS ESSENTIAL.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD .
Other Protective Equipment:FULL PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ:IN CASE OF H2O POLLUTION, CALL LOC AUTHORITIES. FIRST AID
    PROC:USUALLY OCCURS. IF THIS HAS NOT OCCURED, & IF VICTIM IS FULLY
    ALERT INDUCE EMESIS W/SYRUP OF IPECAC, FOLLOWED BY SLURRY OF ACTI
    VATED CHARCOAL & CALL EMERGENCY MED CARE. NOTE TO MD:SYRUP OF
    IPECAC: 30 ML FOR ADULTS 12 YRS & OLDER, 15 ML (ING 5)

==================  Physical/Chemical Properties  ==================

HCC:T4
Boiling Pt:B.P. Text:212F,100C
Spec Gravity:1.069 (H2O=1)
pH:8.0
Solubility in Water:100%
Appearance and Odor:LIQUID WITH PHENOLIC ODOR.
Percent Volatiles by Volume:81

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
DO NOT MIX WITH ACIDIC MATERIALS - RUINS PRODUCT.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NOXIOUS FUMES UNDER FIRE CONDITIONS,
    FOR EXAMPLE: HCI, ORGANO CHLORIDES, NOX AND CO.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISP OF DOT DRUM, WASTE H2O & ANY OTHER WASTE
    ACCORD TO EPA APPROVED METHODS. PESTICIDE:DO NOT CONTAM H2O,
    FOOD/FEED BY STORAGE/DISP. PESTICIDE WASTES ARE TOXIC. IMPROPER
    DISP OF EXCESS PESTICIDE SPRA Y MIXTURE/RINSATE IS A VIOLATION OF
    (ING 10)

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