BREAK-FREE DIV OF SAN/BAR CORP -- BREAK-FREE CLP LIQUID (NON-CHLORINATED FORMULA) -- 9150-01-053-6688
===================== Product Identification ===================== Product ID:BREAK-FREE CLP LIQUID (NON-CHLORINATED FORMULA) MSDS Date:04/04/1997 FSC:9150 NIIN:01-053-6688 === Responsible Party === Company Name:BREAK-FREE DIV OF SAN/BAR CORP Address:1035 S LINWOOD AVE Box:25020 City:SANTA ANA State:CA ZIP:92799-5020 Country:US Info Phone Num:714-953-1900 Emergency Phone Num:714-953-1900 Preparer's Name:DONALD E. YODER CAGE:65983 === Contractor Identification === Company Name:BREAK-FREE INC Address:13386 INTERNATIONAL PARKWAY Box:City:JACKSONVILLE State:FL ZIP:32218 Country:US Phone:800-428-0588/ 904-741-5400 CAGE:65983 ============= Composition/Information on Ingredients ============= Ingred Name:DIBASIC ESTER #1 Fraction by Wt: 5% Other REC Limits:NONE RECOMMENDED Ingred Name:SYNTHETIC OILS, ESTERS AND OTHER INGREDIENTS. = Wt:23.7 Other REC Limits:NONE RECOMMENDED Ingred Name:DIBASIC ESTER #1 = Wt:5.3 Other REC Limits:NONE RECOMMENDED Ingred Name:POLYALPHAOLEFIN SYNTHETIC OIL CAS:68037-01-4 Code:F = Wt:65.9 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 Ingred Name:SYNTHETIC ISOPARAFFINIC HYDROCARBONS CAS:64742-47-8 Code:F RTECS #:OA5504000 = Wt:5.1 OSHA PEL:5 MG/M3 ACGIH TLV:5 MG/M3 ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 > 5 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:INHALATION- RESPIRATORY IRRITATION AND DISCOMFORT MAY BE EXPERIENCED. EXCESSIVE INHALATION CAN CAUSE RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS. EYES- POSSIBLE TRANSIENT IRRITATION. SKIN- POSSIBLE SLIGHT TO MODERATE REDNESS. INGESTION- LOW LEVEL OF TOXCITY. MAY CAUSE IRRITATION TO DIGESTIVE TRACT. Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. Effects of Overexposure:INHALATION- DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHES AND POSSIBLE UNCONSCIOUSNESS. ======================= First Aid Measures ======================= First Aid:FOLLOW GOOD INDUSTRIAL HYGIENE PRACTICES. IF SPLASHED IN THE EYES, FLUSH WITH WATER IMMEDIATELY FOR 15 MIN. IF SPILLED ON CLOTHING, REMOVE SOILED CLOTHING & WASH WITH SOAP & WATER/ LAUNDER ALL CONTAMI NATED CLOTHES BEFORE REUSE. IF SWALLOWED, DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNTS OF WATER & SEEK IMMEDIATE MEDICAL ATTENTION. IF INHALED, MOVE TO FRESH AIR. ANESTHETIC OR NARCOTIC E FFECTS COULD OCCUR FROM OVEREXPOSURE TO VAPORS, SO CALL A PHYSICIAN. IF AVAILABLE, GIVE OXYGEN. IF BREATHING STOPS, GIVE MOUTH-TO-MOUTH RESUSCITATION. ===================== Fire Fighting Measures ===================== Flash Point Method:PMCC Flash Point:=94.C, 201.2F Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICALS. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR NIOSH APPROVED, POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS TO AVOID EXPOSURE FROM DECONTAMINATION PRODUCTS. PROPER EYE AND SKIN PROTECTION SHOULD BE USED. IF A SPILL HAS NOT IGNITED, USE WATER SPRAY TO DISPERSE VAPORS AND KEEP CONTAINER COOL. Unusual Fire/Explosion Hazard:AFTER IGNITION, THE USE OF WATER CAN SCATTER THE LIQUID THEREBY POSSIBLE SPREADING THE FIRE. IGNITION MAY ALSO PRODUCE DENSE BLACK SMOKE. ================== Accidental Release Measures ================== Spill Release Procedures:FOR SMALL SPILLS, VACUUM INTO WASTE CONTAINERS OR ABSORB WITH DRY SAND OR ABSORBENT CLOTH. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM OPEN FLAMES OR OTHER IGNITION SOURCES. DO NOT STORE ABOVE 120F. MAINTAIN ADEQUATE VENTILATION & KEEP FROM CHILDREN. Other Precautions:NOTE THAT SOME VAPORS ARE HEAVIER THAN AIR & CAN DISPLACE AIR IN LOW AREAS OR CONFINED SPACES SUCH AS PITS AND TANKS. DO NOT ENTER THOSE AREAS WHERE LARGE QUANTITIES OF VAPORS ARE SUSPECTED OR COLLECT ING UNTIL EXCHANGING THE AIR OR USING BREATHING APPARATUS WITH AN OBSERVER PRESENT FOR POSSIBLE ASSI STANCE. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED FOR NORMAL WORK SITUATION WHERE ADEQUATE VENTILATION IS PROVIDED. USE NIOSH APPROVED SELF-CONTAINED POSITIVE PRESSURE RESPIRATORS FOR EMERGENCIES AND IN SITUATIONS WHERE AIR MAY BE DISPLA CED BY VAPORS OR IN CONFINED AREAS WHERELOW AIR EXCHANGE RATES. Ventilation:NO SPECIAL REQUIREMENTS. USE LOCAL EXHAUST IF TLV IS EXCEEDED OR MECHANICAL(GENERAL) VENTILATION IN CLOSED AREAS. Protective Gloves:POLYETHYLENE, NEOPRENE, PVC. Eye Protection:NORMALLY NONE REQUIRED. WEAR SPLASH PROOF GOGGLES. Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN IN MANUFACTURING AREAS. PERSOANL PROTECTIVE CLOTHING & USE OF EQUIPMENT MUST BE IN ACCORDANCE WITH 29 CFR 1910.132 AND 29 CFR 1910.133. Work Hygienic Practices:DO NOT SMOKE, EAT OR DRINK WHILE USING THIS PRODUCT. WASH HNADS WITH SOAP AND WATER BEFORE SMOKING, EATING, DRINKING OR USING THE TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHIHG BEFORE RESUE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:V6 Boiling Pt:=190.5C, 374.9F Volatile Org Content %:5 Spec Gravity:0.87 Solubility in Water:NIL Appearance and Odor:LIGHT AMBER COLOR, MILD ODOR. Percent Volatiles by Volume:11 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:SPARKS, HOT SPOTS, WELDING, FLAMES AND CIGARETTES. Hazardous Decomposition Products:OXIDES OF CARBON, SULFUR AND NITROGEN AND PTFE POWDER. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECOVERED LIQUIDS MAY BE REPROCESSED OR INCINERATED OR TREATED IN A PERMITTED HAZARDOUS WASTE MANAGEMENT FACILITY. CARE MUST BE TAKEN WHEN USING OR DISPOSING OF CHEMICAL MATERIALS AND/OR THEIR CONTAIN ERS TO PREVENT ENVIRONMENTAL CONTAMINATION. DISPOSE OF WASTE IN ACCORDANCE WITH CLEAN AIR ACT, RCRA, & FEDERAL, STATE OR LOCAL LAWS & REGULATIONS. ===================== Regulatory Information ===================== SARA Title III Information:ALL SARA TITLE III MATERIALS HAVE BEEN REPORTED. Federal Regulatory Information:ALL INGREDIENTS CONTAINED IN THIS FORMULA ARE LISTED ON THE TOXIC SUBSTANCE CONTROL ACT (TSCA) CHEMICAL INVENTORY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.