HACH CO. -- 1072 ALKALINE IODIDE-AZIDE REAGENT -- 6810-00D001386
===================== Product Identification ===================== Product ID:1072 ALKALINE IODIDE-AZIDE REAGENT MSDS Date:07/15/1986 FSC:6810 NIIN:00D001386 === Responsible Party === Company Name:HACH CO. Address:100 DAYTON RD Box:907 City:AMES State:IA ZIP:50010-6402 Country:US Info Phone Num:303-669-3050 Emergency Phone Num:515-232-2533 CAGE:91224 === Contractor Identification === Company Name:HACH CO Address:5600 LINDBERGH DR Box:389 City:LOVELAND State:CO ZIP:80539 Country:US Phone:970-669-3050/ 303-623-5716 CAGE:91224 ============= Composition/Information on Ingredients ============= Ingred Name:LITHIUM HYDROXIDE MONOHYDRATE CAS:1310-66-3 RTECS #:OJ6307080 Fraction by Wt: <65% Other REC Limits:NONE SPECIFIED Ingred Name:POTASSIUM IODIDE CAS:7681-11-0 RTECS #:TT2975000 Fraction by Wt: <40% Other REC Limits:NONE SPECIFIED Ingred Name:SODIUM AZIDE (SARA III) CAS:26628-22-8 RTECS #:VY8050000 Fraction by Wt: <5% Other REC Limits:100 PPB OSHA PEL:S, C 0.1 PPM(HN3) ACGIH TLV:C 0.11 PPM; 9394 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 340MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: PRODUCT IS CORROSIVE TO SKIN, EYES AND RESPIRATORY TRACT. HARMFUL IF SWALLOWED, MAY CAUSE CNS EFFECTS. CHRONIC: DERMATITIS, IRRITATION OF MUCOUS MEMBRANES, CNS EFFECTS. Explanation of Carcinogenicity:MFR LISTS AS "POTENTIAL CARCINOGEN". Effects of Overexposure:CAUSES BURNING, DIZZINESS, NAUSEA, CENTRAL NERVOUS SYSTEM DEPRESSION, COMA, DEATH. CHRONIC IODINE EXPOSURE MAY CAUSE SKIN RASH, RUNNY NOSE. Medical Cond Aggravated by Exposure:RESPIRATORY & SKIN DISORDERS. PRODUCT MAY ALSO LOWER BLOOD PRESSURE. ======================= First Aid Measures ======================= First Aid:EYES/SKIN: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. REMOVE CONTAMINATED CLOTHING. CALL A PHYSICIAN. INGESTION: IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER AND AT LEAST 1 OZ. OF VINEGAR MIXED WITH WA TER. GET MEDICAL IMMEDIATE ATTENTION. INHALED: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF BREATHING STOPPED. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NONFLAMMABLE Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. Unusual Fire/Explosion Hazard:MAY EMIT TOXIC FUMES OF IODINE AND IODINE COMPOUNDS IN FIRE. ================== Accidental Release Measures ================== Spill Release Procedures:PLACE IN A BEAKER, DILUTE WITH WATER, NEUTRALIZE WITH 6M HYDROCHLORIC ACID AND FLUSH DOWN DRAIN WITH EXCESS OF WATER. Neutralizing Agent:HYDROCHLORIC ACID OR ACETIC ACID ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL, DRY AREA AWAY FROM INCOMPATIBLE MATERIALS. KEEP TIGHTLY CLOSED. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. HMIS: IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR EMERGENCY OCCURS; USE NIOSH/MSHA APPROVED RESPIRATOR. USE IAW 29 CFR 1910.134 AND RESPIRATOR Ventilation:USE FUME HOOD TO MAINTAIN EXPOSURE BELOW REGULATORY LIMITS. Protective Gloves:RUBBER Eye Protection:SAFETY GLASSES Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:C2 Melt/Freeze Pt:M.P/F.P Text:230F,110C Spec Gravity:1.94 (WATER=1) Solubility in Water:APPRECIABLE Appearance and Odor:WHITE CRYSTALLINE SOLID; NO DISTINCTIVE ODOR, PH OF 5% SOLN=12.6 Corrosion Rate:AL 0.248 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS. Stability Condition to Avoid:EXPOSURE TO HEAT OR FLAMES, EXCESS MOISTURE; CONTACT WITH STRONG MINERAL ACIDS, STRONG OXIDIZING AGENTS. Hazardous Decomposition Products:FUMES OF IODINE AND IODINE COMPOUNDS ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. EPA WASTE NUMBER P105 MAY APPLY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.