SHERWIN-WILLIAMS CO-DIVERSIFIED BRANDS -- INDUSTRIAL MAINTENANCE & TOUCH UP SPRAY COLORS. -- 8010-00-584-3150
===================== Product Identification ===================== Product ID:INDUSTRIAL MAINTENANCE & TOUCH UP SPRAY COLORS. MSDS Date:09/01/1996 FSC:8010 NIIN:00-584-3150 Status Code:A === Responsible Party === Company Name:SHERWIN-WILLIAMS CO-DIVERSIFIED BRANDS Address:101 PROSPECT AVE. NW City:CLEVELAND State:OH ZIP:44115-1042 Country:US Info Phone Num:800-832-2541 Emergency Phone Num:1-216-566-2917 CAGE:09800 === Contractor Identification === Company Name:SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC. Address:26300 FARGO AVENUE Box:City:BEDFORD HEIGHTS State:OH ZIP:44146 Country:US Phone:216-292-7400 OR 216-595-8634 CAGE:09800 ============= Composition/Information on Ingredients ============= Ingred Name:PROPANE VP= 760 MM HG CAS:74-98-6 RTECS #:TX2275000 = Wt:14. OSHA PEL:1000 PPM Ingred Name:BUTANE VP= 760 CAS:106-97-8 RTECS #:EJ4200000 = Wt:6. OSHA PEL:800 PPM ACGIH TLV:800 PPM Ingred Name:TOLUENE VP= 22.0 CAS:108-88-3 RTECS #:XS5250000 OSHA PEL:100 PPM OSHA STEL:100 PPMM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:XYLENE VP= 5.9 CAS:1330-20-7 RTECS #:ZE2100000 = Wt:13. OSHA PEL:100 PPM OSHA STEL:100 PPM ACGIH TLV:100 PPM ACGIH STEL:150 PPMM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:ETHYLBENZENE VP= 7.1 CAS:100-41-4 RTECS #:DA0700000 = Wt:2. OSHA PEL:100 PPMM OSHA STEL:125 PPMM ACGIH TLV:100 PPM ACGIH STEL:125 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:T-BUTANOL VP= 5.5 CAS:75-65-0 RTECS #:EO1925000 OSHA PEL:50 PPM Ingred Name:ACETONE VP= 180 CAS:67-64-1 RTECS #:AL3150000 = Wt:35. OSHA PEL:750 PPM OSHA STEL:1000 PPMM ACGIH TLV:750 PPMM ACGIH STEL:1000 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ETHYL KETONE VP= 70 CAS:78-93-3 RTECS #:EL6475000 = Wt:3. OSHA PEL:200 PPMM OSHA STEL:300 PPM ACGIH TLV:200 PPM ACGIH STEL:300 PPMM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:METHYL ISOBUTYL KETONE VP= 18.0 CAS:108-10-1 RTECS #:SA9275000 OSHA PEL:50 PPMM OSHA STEL:75 PPMM ACGIH TLV:50 PPM ACGIH STEL:75 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:1-METHOXY-2-PROPANOL ACETATE VP= 1.60 CAS:108-65-6 RTECS #:AI8925000 = Wt:7. Ingred Name:AMORPHOUS PRECIPITATED SILICA CAS:112926-00-8 RTECS #:VV7315000 = Wt:1. OSHA PEL:6 PPM ACGIH TLV:10 PPM Ingred Name:BARIUM SULFATE CAS:7727-43-7 RTECS #:CR0600000 = Wt:0. OSHA PEL:10(5)MG/M3(DUST) ACGIH TLV:10 MG/M3 Ingred Name:TITANIUM DIOXIDE CAS:13463-67-7 RTECS #:XR2275000 = Wt:7. OSHA PEL:10(5)MG/M3FRACTION ACGIH TLV:10 MG/M3 Ingred Name:CARBON BLACK CAS:1333-86-4 RTECS #:FF5800000 OSHA PEL:3.5 MG/M3 ACGIH TLV:3.5 MG/M3 ===================== Hazards Identification ===================== Health Hazards Acute and Chronic:(TO MINIMIZE EXPOSURE FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION, AND PERSONAL) ACUTE HEALTH HAZARDS: IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION . EXTREME OVEREXPOSURE MAY RESULT IN UNCONSCOIUSNESS AND DEATH. HEADACHE, DIZZINESS, NUASEA, AND LOSS OF COORDINATION ARE INDICATIONS OF OXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND I TCHING OR BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. Effects of Overexposure: CHRONIC HEALTH HAZARDS: NO INGREDIENT IN THESE PRODUCTS IS AN IARC, NTP< OR OSHA LISTED CARCINOGEN. PROLONGED OR OVEREXPOSURE TO SOLVENT INGREDIENTS IN SECTION II MAY CAUSE ADVERSE EFFECTS TO THE LIVER AND URINARY SYSTEMS. METHYL ETHYL KETONE MAY INCREASE THE NERVOUS SYSTEMAFFECTS OF OTHER SOLVENTS. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXP OSURE LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. ===================== Fire Fighting Measures ===================== Flash Point:<-17.6C, 0.F <0F Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM. Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITIONOR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY XPLODE(DUE-BUILDUP OF PRSSURE)WH-XPOSED-XTREME HEAT.ISLATE F/HEAT,ELECTRICAL EQIPMENT,SPRKS&OPEN FLME.APPLICATION-HOT SRFACES REQIRES SPECIAL PRCAUTIONS.DURING EMERGNCY CNDITIONS OVERXPOSURE-DECOMP.PRDUCTS MAY CAUSE HEALTH HAZARD.SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.GET MEDICAL ATTENTION. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND REMOVE WITH INERT ABSORBENT. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID HEAT,SPARKS&OPEN FLAME.VAPORS?IGNITE EXPLOSIVELY.DURING USE&UNTIL VAPORS ARE GONE,KEEP AREA VENTILATED-DON'T SMOKE. Other Precautions:XTINGUISH FLMES.PILOT LGHTS,&HEAT.TURN OF FLMES,ELECTRICL EQIPMENT&SOURCS OF IGNTION.CONSULT EPA CODE.USE APPRVED BONDING&GROUNDING PROCEDRES.DON'T PUNCTRE,INCNERATE,/XPOSE-TEMP ABOVE170'F.KEEP F/SUNL GHT,RDIOSTORM,STOVES,HOT WTER,HEAT SOURCS CAUSE CNTAINER-BURST.DON'T TKE INTRNALLY.KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST INGREDIENTS. Ventilation:LOCAL EXHAUST PREFERABLE.GENERAL EXHAUST ACCEPTABLE IF EXPOSURE-MATERIALS IN SECTION II IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS. Protective Gloves:FOR LONG OR REPEATED CONTACT, WEAR CHEMICAL RESISTANT GLOVES. Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDE SHIELDS. Other Protective Equipment:?CONTAIN NUISANCE PARTICULATES("AS DUST"SECTION II)WHICH?PRESENT@HAZARDOUS LEVELS DURING SANDING/ABRADING.IF NO DUSTS LISTED SECTION II,LIMITS ACGIH TLV,10MG/M3(DUST),OSHA PEL15MG/M3,5MG/M3(FRACTION Work Hygienic Practices:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. WASH HANDS AFTER USING. Supplemental Safety and Health WHEN SANDING,WIREBRUSHING,ABRADING,BURNING/WELDING DRIED FILM,WEARPARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION AGAINST NON-VOLATILE INGREDIENTS.WHEN SANDING/ABRADING DRIED FILM, WEAR D UST/MIST RESPIRATOR APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED,UNDERLYING PAINT,/ABRASIVE. ================== Physical/Chemical Properties ================== Boiling Pt:<150.C, 302.F B.P. Text:<0-302F Vapor Density:>AIR Evaporation Rate & Reference:FASTER THAN ETHER ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES Hazardous Decomposition Products:CO2, CO, OXIDES OF METALS IN INGREDIENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:MAY BE HAZARDOUS UNDER RCRA10CFR261.MUST BE TREATED FOR IGNITABILITY-DETERMINE APPLICABLE EPA HAZARDOUS WASTE NUMBERS.WASTES /PRODUCTS CONTAINING METHYL ETHYL KETONE/COPPER MAY REQUIRE TESTING FOR ACC EPTABILITY.DON'T INCINERATE.DEPRESSURIZE CONTAINER.DISPOSE OF ACCORDING-FEDERAL,STATE,&LOCAL REGULAT IONS REGARDING POLLUTION. ===================== Regulatory Information ===================== SARA Title III Information:THE FOLLOWING INGREDIENTS ARE SUBJECT TO REPORTING REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT (SARA) SECTION 313, 40 CFR PART 372.65C 1) TOLUENE 2) ETHYLBENZENE 3) XYLENE 4 ) 1-BUTANOL 5) METHYL ETHYL KETONE 6) METHYL ISOBUTYL KETONE State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING! THESE PRODUCTS CONTAIN A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.