SCHOLLE CORPORATION -- BATTERY FLUID, ACID (ELECTROLYTE) -- 6810-01-418-1697
===================== Product Identification ===================== Product ID:BATTERY FLUID, ACID (ELECTROLYTE) MSDS Date:07/01/1999 FSC:6810 NIIN:01-418-1697 Status Code:A === Responsible Party === Company Name:SCHOLLE CORPORATION Address:200 W. NORTH AVE., City:NORTHLAKE State:IL ZIP:60164 Country:US Info Phone Num:708-562-7290 Emergency Phone Num:800-424-9300 Chemtrec Ind/Phone:(800)424-9300 CAGE:TO531 === Contractor Identification === Company Name:SCHOLLE CORP Address:200 W NORTH AVE Box:City:MELROSE PARK State:IL ZIP:60164-2402 Country:US Phone:708-562-7290 Contract Num:SP0450-00-M-D577 CAGE:97807 Company Name:SCHOLLE CORPORATION Address:200 W. NORTH AVE., Box:City:NORTHLAKE State:IL ZIP:60164 Country:US Phone:708-562-7290 CAGE:TO531 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID CAS:7664-93-9 RTECS #:WS5600000 Minumum % Wt:34. Maxumum % Wt:36. OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:3 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:64. Maxumum % Wt:66. ===================== Hazards Identification ===================== LD50 LC50 Mixture:ACUTE ORAL LD 2,140 MG/KG (RABBIT) Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: 3D DEGREE BURNS. SEVERE RESPIRATORY, SKIN AND EYE IRRITANT. BRONCHITIS, LARYNGEAL AND PULMONARY EDEMA MAY RESULT. Explanation of Carcinogenicity:IARC: A LIMITED STUDY OF REFINERY WORKERS SUGGESTED A POSSIBLE LINK BETWEEN SULFURIC ACID EXPOSURE & LARYNGEAL CANCER. HOWEVER, DUE TO THE SMALL NUMBER OF WORKERS INVOLVED & THE MIXED EXPOSURE TO SEVE RAL OTHER MATERIALS INCLUDING DIETHYLSULFATE (LISTED CARCINOGEN BY IARC & NTP) THERE IS NO CAUSE-EFFECT RELATIONSHIP INFERRED. Effects of Overexposure:PRICKLING OR BURNING SENSATION OF SKIN AND MUCOUS MEMBRANES. COUGHING, SNEEZING, TIGHTNESS OF CHEST. DIFFICULTY IN BREATHING. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXITING DISEASE OF THE LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE FROM EXPOSURE. CPR IF INDICATED. GIVE OXYGEN. EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. HOLD LIDS OPEN. SKIN: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING & SHOES. INGESTION: DO NOT INDUCE VOMITING! GIVE LARGE AMOUNTS OF MILK, MILK OF MAGNESIA OR TABLE OIL OR FRESH EGGS. USE WATER IF NOTHING ELSE AVAILABLE. RINSE MOUTH OFTEN. ===================== Fire Fighting Measures ===================== Extinguishing Media:DRY CHEMICAL OR CO2 SMALL FIRES. WATER FOG, LARGE FIRES. Fire Fighting Procedures:DO NOT DIRECT WATER INTO ACID TANKS. COOL OUTSIDE OF TANK WITH WATER. WEAR FULL-FACE SELF-CONTAINED RESPIRATOR, RUBBERIZED OUTER WEAR, GLOVES, BOOTS. Unusual Fire/Explosion Hazard:SULFURIC ACID WILL NOT BURN BUT START FIRES WITH ORGANIC MATERIAL, NITRATES, CARBIDES, CHLORATES, METAL POWDERS. FLAMMABLE HYDROGEN GAS FORMS WHEN ACID CONTACTS MOST METALS. HYDROGEN MAY ACCUMULATE IN CONTAINERS. SPILLOVER IN SEWERS MAY GENERATE HYDROGEN GAS OR TOXIC SULFIDES. WATER TO ACID CAUSES HEAT & SPLATTERING. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR FULL ACID-PROTECTIVE GEAR. REMOVE SOURCES OF IGNITION. FLUSH AWAY BY FLOODING WITH WATER APPLIED QUICKLY TO ENTIRE SPILL. NEUTRALIZE SPILLS WITH LIME OR SODA ASH, FLUSH TO ON-SITE WASTE WATER TRE ATMENT SYSTEM. DIKE LARGE SPILLS. DO NOT WASH INTO STORM OR SANITARY SEWER SYSTEM. Neutralizing Agent:LIME OR SODA ASH. ====================== Handling and Storage ====================== Handling and Storage Precautions:SEE "UNUSUAL FIRE & EXPLOSION HAZRDS." DO NOT STORE NEAR ORGANICS. HYDROGEN MAY BE GENERATED INSIDE DRUMS & TANKS; AVOID FLAMES & SPARKS. Other Precautions:NEVER ADD WATER TO CONTAINERS OF ACID. FOR SPILLS, BEWARE OF ACID REACITON IN SEWERS THAT MAY PRODUCE FLAMMABLE HYDROGEN GAS OR TOXIC SULFIDES. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHEN NEEDED USE NIOSH OR MSHA APPROVED HALF OR FULL-FACE MASK WITH ACID GAS CARTRIDGE. FOR HIGH CONCENTRATIONS, USE SELF-CONTAINED BREATHING UNIT. Ventilation:REQUIRED. LOCAL EXHAUST: YES. MECHANICAL: VENTILATE STORAGE TANKS BEFORE ENTRY. Protective Gloves:RUBBER. Eye Protection:CHEMICAL GOGGLES OR FULL-FACE SHIELD. Other Protective Equipment:RUBBER SAFETY SHOES/BOOTS. RUBBER APRON OR FULL SUIT IF SPLASHES LIKELY. Work Hygienic Practices:PROHIBIT SMOKING. PROVIDE SAFETY SHOEWERS/EYE WASHES NEAR WORK SITE. TRAIN EMPLOYEES IN CHEMICAL HANDLING PRACTICES. Supplemental Safety and Health SPEED IN REMOVING ACID IS ESSENTIAL. TREAT MOST URGENT SYMPTOMS FIRST: CESSATION OF BREATHING, EYE INJURY, SKIN CONTACT, SHOCK. SEEK MEDICAL ASSISTANCE EVEN IF INJURY APPEARS SLIGHT. GIVE PHYSICIAN DE TAILED ACCOUNT OF INCIDENT. ================== Physical/Chemical Properties ================== HCC:C1 Boiling Pt:=135.C, 275.F Melt/Freeze Pt:=-62.2C, -80.F Vapor Pres:<1MMHG AT 100F (37.8C) Vapor Density:3.4(AIR=1) Spec Gravity:1.265 (WATER=1) pH:<1 (1% SOLN) Solubility in Water:SOLUBLE IN ALL PROPORTION Appearance and Odor:CLEAR, COLORLESS LIQUID ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG CORROSIVE AGENT WILL ATTACK MOST METALS. CONTACT WITH ORGANICS, NITRATES, CARBIDES, CHLORATES, ETC. MAY CAUSE IGNITION. ALLYL COMPOUNDS AND ALDEHYDES UNDERGO POLYMERIZATION - POSSIBLE VIOLENT. Stability Condition to Avoid:CONTACT WITH METALS, ORGANICS. Hazardous Decomposition Products:SULFUR OXIDES AT HIGH TEMPERATURE. REACTS WITH ABOVE TO FORM HYDROGEN CYANIDE AND HYDROGEN SULFIDE. Conditions to Avoid Polymerization:ALL CONTACT WITH ORGANIC SUBSTANCES AND MOST METALS. =================== Toxicological Information =================== Toxicological Information:ORAL LD50=2140 MG/KG. SKIN AND EYE IRRITATION (RABBIT). CORROSIVE INHALATION 1 HOUR LC50 RAT: 347 PPM. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:FLUSH AS ABOVE. NEUTRALIZE WITH LIME OR SODA ASH, (A MINIMUM OF 5.2 POUNDS SODA ASH PER GALLON OF BATTERY FLUID, ELECTROLYTE). CONSULT REGULATIONS. EPA HAZARDOUS WASTE D002 - CORROSIVE AND D003 - REAC TIVE IF DISCARDED WITHOUT PRIOR NEUTRALIZATION. =================== MSDS Transport Information =================== Transport Information:BATTERY FLUID, ACID, 8, UN2796, PGII. ===================== Regulatory Information ===================== SARA Title III Information:BATTERY FLUID, ACID CONTAINS APPROXIMATELY 35% BY WEIGHT OF H2SO4 (CAS# 7664-93-9) AND IS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMMENDMENTS AND REAUTHORIZA TION ACT (SARA) OF 1986. IT IS ALSO SUBJECT TO THE REPORTING REQUIREMENTS OF 40 CFR PART 372. Federal Regulatory Information:REPORTABLE QUANTITY: 1000 LB/454 KG AS H2SO4. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.