E I DUPONT DE NEMOURS & CO, FREON PROD -- FREON 116 REFRIGERANT -- 6830-00-181-7755
===================== Product Identification ===================== Product ID:FREON 116 REFRIGERANT MSDS Date:08/31/1992 FSC:6830 NIIN:00-181-7755 === Responsible Party === Company Name:E I DUPONT DE NEMOURS & CO, FREON PROD Address:1007 MARKET ST City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-9442 Emergency Phone Num:800-441-3637/800-424-9300(CHEMTREC) Preparer's Name:W.J.BROCK CAGE:5P414 === Contractor Identification === Company Name:E I DUPONT DE NEMOURS & CO, FREON PROD (REPLACED BY 73925) Address:1007 MARKET ST Box:City:WILMINGTON State:DE ZIP:19899 Country:US Phone:800-441-3637-MED 800-424-9300-TRAN CAGE:5P414 ============= Composition/Information on Ingredients ============= Ingred Name:HEXAFLUOROETHANE (FREON 116) CAS:76-16-4 RTECS #:KI4110000 Fraction by Wt: 100% Other REC Limits:1000 PPM 8 HRS TWA ===================== Hazards Identification ===================== LD50 LC50 Mixture:LC50 (RAT) > 800000 PPM/4HR Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION OF HIGH CONCENTRATIONS IS HARMFUL AND MAY CAUSE TEMPORARY ALTERATION OF THE HEART'S ELECTRICAL ACTIVITY, TEMPORARY NERVOUS SYSTEM DEPRESSION WITH ANESTHETIC EFFECTS, UNCONSCIOUSNESS, OR DEATH. INTENTIONAL MISUSE MAY CAUSEDEATH WITHOUT WARNING. LIQUID CONTACT CAN CAUSE FROSTBITE. CHRONIC: NONE NOTED. Explanation of Carcinogenicity:NOT APPLICABLE. Effects of Overexposure:EYES: IRRITATION, TEARING, BLURRED VISION. SKIN: TEMPORARY TINGLING, NUMBNESS, COLDNESS, DRYING OF SKIN. INHALATION: NAUSEA, HEADACHE, WEAKNESS, DIZZINESS, CONFUSION, INCOORDINATION, LOSS OF CONSCIOUS NESS, IRREGULAR PULSE, PALPITATIONS. Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING DISEASES OF THE CENTRAL NERVOUS SYSTEM OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR, IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICI AN. SKIN: FLUSH WITH WATER FOR AT LEAST15 MINUTES. TREAT FOR FROSTBITE IF NECESSARY BY GENTLY WARMING THE AFFECTED AREA. GET MEDICAL ATTENTION IF IRRITATION IS PRESENT. ===================== Fire Fighting Measures ===================== Flash Point Method:TOC Flash Point:NONE Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. CYLINDERS MAY RUPTURE OR RELEASE UNDER FIRE CONDITIONS. ================== Accidental Release Measures ================== Spill Release Procedures:REMOVE PERSONNEL, VENTILATE AREA, ESPECIALLY IN LOW AREAS WHERE VAPOR MIGHT COLLECT, REMOVE OPEN FLAMES. WEAR SELF-CONTAINED BREATHING APPARATUS. STOP LEAK IF SAFE TO DO SO. OTHERWISE, LET EVAPORATE. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE CONTAINERS IN CLEAN DRY AREA. DO NOT HEAT ABOVE 125F. Other Precautions:AVOID BREATHING HIGH CONCENTRATIONS OF VAPOR. AVOID CONTACT OF SKIN OR EYES WITH LIQUID OR COLD VAPORS. USE WITH ADEQUATE VENTILATION TO KEEP EMPLOYEE EXPOSURE BELOW RECOMMENDED LIMITS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS OF USE. SELF-CONTAINED BREATHING APPARATUS IS REQUIRED IF A SPILL OCCURS. Ventilation:MECHANICAL VENTILATION IN LOW OR ENCLOSED PLACES. LOCAL EXHAUST WHEN LARGE AMOUNTS ARE RELEASED. Protective Gloves:LINED LEATHER GLOVES. Eye Protection:CHEMICAL SPLASH GOGGLES. Other Protective Equipment:NONE. Work Hygienic Practices:STANDARD PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health NOTE TO PHYSICIAN: BECAUSE OF POSSIBLE DISTURBANCES OF CARDIAC RHYTHM, CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE, SHOULD BE USED WITH SPECIAL CAUTION IN SITUATIONS OF EMERGENCY LIFE SUPPORT. ================== Physical/Chemical Properties ================== HCC:G3 Boiling Pt:B.P. Text:-109F,-78C Vapor Pres:439 PSIA Vapor Density:4.8 Spec Gravity:1.57 @ -109F Evaporation Rate & Reference:RAPID, PER MANUFACTURER. Solubility in Water:SLIGHT Appearance and Odor:CLEAR, COLORLESS, LIQUEFIED GAS, SLIGHT ETHEREAL ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI OR ALKALINE EARTH METALS, POWDERED ALUMINUM, ZINC, BERILLIUM, ETC. Stability Condition to Avoid:HIGH TEMPERATURES, OPEN FLAMES, GLOWING METAL SURFACES. Hazardous Decomposition Products:HYDROFLUORIC ACID, POSSIBLE CARBONYL FLUORIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECLAIM BY DISTILLATION OR REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY. COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.